科技和产业2024,Vol.24Issue(5) :286-290.

Fenton法预处理合成革废水的去除研究

Study on Removal of Synthetic Leather Wastewater Pretreatment by Fenton Process

王来春 钱佳 熊晓敏 许柯 王庆
科技和产业2024,Vol.24Issue(5) :286-290.

Fenton法预处理合成革废水的去除研究

Study on Removal of Synthetic Leather Wastewater Pretreatment by Fenton Process

王来春 1钱佳 2熊晓敏 1许柯 3王庆1
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作者信息

  • 1. 南京大学宜兴环保研究院,江苏宜兴 214200
  • 2. 江苏中宜金大分析检测有限公司,江苏宜兴 214200
  • 3. 南京大学宜兴环保研究院,江苏宜兴 214200;南京大学环境学院,南京 210023
  • 折叠

摘要

合成革废水中含有大量的二甲基甲酰胺(DMF)等有机污染物,对生物具有毒性危害.采用单因素试验方法,获得Fenton反应对DMF处理最佳工艺参数为pH=3、过氧化氢(H2O2)与化学需氧量(CODCr)的质量比m=6.69、H2O2与亚铁离子的摩尔比n=8及反应时间t=120 min,DMF的平均去除率达96.18%.在此基础上,利用Design-Expert软件中的响应面实验设计原理,设计三因素三水平共17组实验,进一步研究确定上述参数对Fenton法预处理合成革废水CODCr的去除效果.设计并制作针对DMF皮革废水有良好降解效果的Fenton 一体化、H2O2和FeSO4精准投加、pH精准调控的 自动控制系统及集成反应设备,合成革废水的CODCr和DMF的平均去除率为71.87%和 95.78%.

Abstract

Synthetic leather wastewater contains a lot of organic pollutants such as dimethylformamide(DMF),which is toxic to organisms.Single factor test method is adopted.The optimal process parameters of Fenton reaction for DMF treatment include pH=3,mass ratio of hydrogen peroxide(H2O2)to chemical oxygen demand(CODor)m=6.69,molar ratio of H2O2 to ferrous ion n=8 and reaction time t=120 min.The average removal rate of DMF is 96.18%.On this basis,using the experimental design principle of response surface in Design-Expert software,17 groups of experiments with three factors,three levels and three levels were designed,and further study was conducted to determine the removal effect of the above parameters on CODCr of Fenton pretreatment synthetic leather wastewater The automatic control system with Fenton integration,H2O2 and FeSO4 precision control and integrated reaction equipment with good degradation effect of DMF leather wastewater are designed and produced.The average removal rate of CODCr and DMF of synthetic leather wastewater is 71.87%and 95.78%.

关键词

Fenton反应/合成革废水/二甲基甲酰胺(DMF)/自动控制系统

Key words

Fenton reaction/synthetic leather wastewater/Dimethylformamide(DMF)/automatic control system

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基金项目

江苏省重大科技示范项目(BE 2023687)

出版年

2024
科技和产业
中国技术经济学会

科技和产业

影响因子:0.361
ISSN:1671-1807
参考文献量11
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