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水合酸性低共熔溶剂对SCR废催化剂的除砷性能研究

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采用水合酸性低共熔溶剂(Hydrated-Acidic Deep-Eutectic Solvent,HDES)进行选择性催化还原(Se-lective Catalytic Reduction,SCR)废催化剂的除砷性能研究,探讨HDES的氢键供体类型、不同摩尔比、含水率、反应温度和反应时间等因素对除砷效率的影响.研究发现,含水率90%的氯化胆碱-磷酸(摩尔比1∶3)的HDES在90℃水中热反应50 min,除砷效率可达到99.75%,具有良好的循环稳定性.结果表明:HDES可高效去除SCR废催化剂中砷元素,并且TiO2的载体结构保持稳定.这项研究对加强我国SCR催化剂处理技术、提升环境保护水平、促进资源的循环利用具有至关重要的作用.
Research on the Arsenic Removal Performance of Hydrated-Acidic Deep-Eutectic Solvent for SCR Waste Catalyst
The article investigates the arsenic removal performance by using hydrated-acidic deep-eutectic solvents(HDES)for Selective Catalytic Reduction(SCR)waste catalysts,exploring the effects of factors such as hydrogen bond donor types,different molar ratios,water content,reaction temperature,and reaction time on arsenic removal efficiency of HDES.The research found that HDES with 90%moisture content of choline chloride phosphate(mo-lar ratio 1∶3)can achieve a arsenic removal efficiency of 99.75%after 50 minutes of hydrothermal reaction at 90℃,demonstrating good cycling stability.The results indicate that HDES can efficiently remove arsenic from SCR waste catalysts while maintaining the stability of the TiO2 support structure.This research plays a crucial role in en-hancing China's SCR catalyst treatment technology,improving environmental protection levels,and promoting re-source recycling.

SCR waste catalystArsenic poisoningHydrated-acid deep-eutectic solventArsenic removalTiO2 carrier structure

方海峰、张洪雨、史伟伟、秦恒飞、孟娟

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江苏肯创催化剂再生技术有限公司 江苏 常州 213200

江苏理工学院资源与环境工程学院 江苏 常州 213001

SCR废催化剂 砷中毒 水合酸性低共熔溶剂 除砷 TiO2载体结构

2024

科技资讯
北京国际科技服务中心 北京合作创新国际科技服务中心

科技资讯

影响因子:0.51
ISSN:1672-3791
年,卷(期):2024.22(24)