昆明学院学报2024,Vol.46Issue(6) :56-61,86.DOI:10.14091/j.cnki.kmxyxb.2024.06.008

一种三苯胺基氟硼化合物光学性能及潜指纹成像研究

Research on the Optical Properties and Latent Fingerprint Imaging of a Triphenylamine-Based Difluoroboron Compound

杜玉松 陈春琳 董官苣 田佳壮 高树林 杨艳华
昆明学院学报2024,Vol.46Issue(6) :56-61,86.DOI:10.14091/j.cnki.kmxyxb.2024.06.008

一种三苯胺基氟硼化合物光学性能及潜指纹成像研究

Research on the Optical Properties and Latent Fingerprint Imaging of a Triphenylamine-Based Difluoroboron Compound

杜玉松 1陈春琳 1董官苣 1田佳壮 1高树林 1杨艳华1
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作者信息

  • 1. 昆明学院化学化工学院云南省金属有机分子材料与器件重点实验室,云南 昆明 650214
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摘要

二氟化硼化合物不仅具有优异的光物理性质,而且在光电功能材料领域具有广泛应用.为进一步探究二氟化硼化合物的应用,以吩噻嗪为原料,经亲核取代反应、还原反应、亲核缩合反应和配位反应,合成一种含有三苯胺和吩噻嗪基团的二氟化硼化合物.在不同极性有机溶剂和四氢呋喃/水混合溶剂中的测试结果表明,该化合物具有分子内电荷跃迁特性和聚集诱导发光活性,并通过量子化学计算对实验结果进行解释.此外,该化合物可作为显影剂,使玻璃板上的潜指纹成像.通过肉眼可清晰地识别出潜指纹图像的部分一级、二级和三级指纹特征细节.

Abstract

The difluoroboron compounds not only exhibit excellent photophysical properties,but also have wide applications in the field of optoelectronic functional materials.In order to further explore the application,a difluoroboron compound containing triphenylamine and phenothiazine groups was synthesized using phenothiazine as raw material orderly through nucleophilic substitution reaction,reduction reaction,nucleophilic condensation reaction,and coordination reaction.The measurement results in different polar organic solvents and tetrahydrofuran/water mixtures showed that it has intramolecular charge transition characteristics and aggregation-induced emission active,and the experimental results were explained by quantum chemical calculations.In addition,it can serve as a developer to image latent fingerprint on glass plates,as well as clearly identify partial first,second,and third fingerprint feature details of latent fingerprint.

关键词

吩噻嗪/二氟化硼化合物/聚集诱导发光/潜指纹成像

Key words

phenothiazine/difluoroboron compound/aggregation-induced emission/latent fingerprint imaging

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出版年

2024
昆明学院学报
昆明学院

昆明学院学报

CHSSCD
影响因子:0.167
ISSN:1674-5639
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