首页|CuO-ZnO复合薄膜/锡掺杂玻璃光波导传感元件在VOCs检测的中的应用

CuO-ZnO复合薄膜/锡掺杂玻璃光波导传感元件在VOCs检测的中的应用

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金属氧化物半导体气敏材料因良好稳定性和优异的光电特性广泛应用于传感器领域.基于掺杂可以调控金属氧化物半导体材料的气敏性,分别以ZnCl2和Zn(NO₃)₂作母体,以Cu(NO₃)₂作掺杂剂制备CuO-ZnO复合材料,并将其通过浸渍提拉法固定于锡掺杂玻璃光波导表面制备出CuO-ZnO复合薄膜/锡掺杂玻璃光波导传感元件;利用光波导技术测试不同原料制备的CuO-ZnO复合薄膜光波导传感元件的气敏性.结果表明,合成复合材料所使用原料以及掺杂剂用量影响传感元件的气敏性;以ZnCl2作母体而制备的CuO-ZnO复合薄膜光波导传感元件的灵敏度高于Zn(NO₃)₂作母体而制备出的CuO-ZnO复合薄膜光波导传感元件;CuO的掺杂提高传感元件对二甲苯气体的选择性,能够检测出体积比为1×10-5的二甲苯气体.
Application of CuO-ZnO Composite Film/Tin Doped Glass Waveguide Sensor for VOCs Detection
Metal oxide semiconductor gas sensing materials are widely used in the sensors fields due to its good stability and excellent optoelectronic properties.And the gas sensing properties of them can be regulated by doping.In this paper,the CuO-ZnO composite materials prepared by sol-gel method which using Cu(NO₃)₂as dopant,ZnCl2 and Zn(NO₃)₂as raw materials,respectively.And the CuO-ZnO as sensing materials prepare the CuO-ZnO composite film/tin doped glass waveguide sensor by sol-dip-coating method.The gas sensitivity of CuO-ZnO composite film optical waveguide sensors prepared from different raw materials were studied.The research results indicated that the amount of raw materials and dopants affects the gas sensitivity of sensors.The sensitivity of CuO-ZnO composite film optical waveguide sensor prepared using ZnCl2 raw materials is higher than that of using Zn(NO₃)₂ raw materials.Doping of CuO improves the selectivity of optical waveguide sensor to xylene gases,and can be detect a volume ratio of 1×10-5 xylene.

optical waveguideVOCs detectionCuO-ZnO composite filmxylene

姑丽各娜·买买提依明、木尼热·吐尔洪、米日古力·莫合买提、古丽巴哈尔·达吾提、阿布力孜·伊米提

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喀什大学化学与环境科学学院,新疆 喀什 844000

喀什大学新疆新型功能材料化学重点实验室,新疆 喀什 844000

阿图什市第一中学,新疆阿图什 845350

新疆大学化学学院,新疆 乌鲁木齐 830046

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光波导传感 VOCs检测 CuO-ZnO复合薄膜 二甲苯

2024

喀什大学学报
喀什师范学院

喀什大学学报

CHSSCD
影响因子:0.178
ISSN:2096-2134
年,卷(期):2024.45(6)