首页|伊犁盆地蒙其古尔砂岩型铀矿床铀矿物特征及其对地浸的指示意义

伊犁盆地蒙其古尔砂岩型铀矿床铀矿物特征及其对地浸的指示意义

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可地浸砂岩型铀矿床矿石中铀元素的赋存形式直接影响铀元素的浸出率,矿石中工艺矿物学特征则影响铀矿物与溶浸液的接触,从而影响铀的溶解反应,查明矿床矿石中铀的赋存形态以及工艺矿物学特征,可为地浸生产中提高铀的浸出率提供参考依据.因此,本次研究以蒙其古尔铀矿床L65-LO勘探线典型矿石为研究对象,通过逐级化 学提取、电子探针(EPMA)、综 合矿物 分析仪(TIMA)等方法,分析了铀元素的赋存形态、存在形式,查明了矿石中铀矿物的类型,以及铀矿物粒度、解离度、连生矿物、孔隙大小等工艺矿物学参数.结果表明:(1)由逐级化学提取分析可知,矿石中活性铀在矿石中占比可达99.5%,铀元素主要以可溶的碳酸盐结合态(50.77%~56.64%)和铁锰氧化物结合态(18.72%~36.08%)存在,说明矿石中的铀元素易于浸出;(2)研究区铀矿物含量高,矿石中的铀矿物占比高达5%,其中沥青铀矿占比4.19%,铀石占比1.56%,主要为易浸出的铀矿物类型;(3)TIMA分析表明铀矿物解离度较低,解离度<10%的沥青铀矿可达77.81%,解离度<10%的铀石高达99.33%,指示铀石的连生组合比沥青铀矿复杂,在地浸中沥青铀矿更易浸出,铀石的浸出效果差.
CHARACTERISTICS OF URANIUM MINERALS FROM THE MENGQIGUER SANDSTONE-TYPE URANIUM DEPOSIT IN THE YILI BASIN AND THE IM-PLICATION FOR IN-SITU LEACHING
The occurrence form of uranium in the ore of in-situ leachable sandstone-type uranium deposits directly impacts the leaching rate of uranium.The process mineralogy characteristics of the ore influence the contact between uranium minerals and the leaching solution,thereby affecting the dissolution reaction of uranium.Characterizing the occurrence form and process mineralogy characteristics of uranium in the ore deposit serves as a valuable reference for enhancing the leaching rate of uranium in in-situ leaching pro-duction.In this study,the typical ore from the L65-L0 exploration line of the Mengchiguer uranium de-posit is taken as the research object.Sequential chemical extraction,electron probe microanalysis(EP-MA),and TESCAN integrated mineralogy analysis(TIMA)are employed to analyze the occurrence state and existence form of uranium elements,as well as uranium mineral types,size,dissociation degree,asso-ciated minerals,pore size,etc.Sequential chemical extraction analysis indicates that the proportion of ac-tive uranium in the ore reaches 99.5%,with uranium primarily in the soluble carbonate binding state(50.77%-56.64%)and the iron and manganese oxide binding state(18.72%-36.08%).This suggests that uranium in the ore is readily extractable.The uranium mineral content in the study area is high,ac-counting for as much as 5%of the ore,with pitchblende constituting 4.19%and coffinite 1.56%.TIMA analysis reveals a low dissociation degree of uranium minerals,with pitchblende having less than 10%dis-sociation reaching 77.81%,and coffinite with less than 10%dissociation reaching 99.33%.This indicates that the association assembly of coffinite is more complex than that of pitchblende.Consequently,in in-si-tu leaching,the leaching efficiency of pitchblende is higher than that of coffinite.

uranium mineralsequential chemical extractionTIMAin-situ leaching of uraniumMengqiguer uranium deposit

李梅、宋昊、王泽鑫、范元清、汤义伟、杜钱敏、周靖、张成江、谭亚辉、张虎军

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成都理工大学,四川成都 610059

地质灾害防治与地质环境保护国家重点实验室,四川成都 610059

地学核技术四川省重点实验室,四川成都 610059

新疆中核天山铀业有限公司,新疆乌鲁木齐 835000

核工业北京化工冶金研究院,北京 101149

核工业二一六大队,新疆乌鲁木齐 830011

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铀矿物 逐级提取 TIMA 地浸采铀 蒙其古尔铀矿床

国家自然科学基金国家自然科学基金成都理工大学珠峰科学研究计划

42173072U19672072021ZF11413

2024

矿物岩石
四川省矿物岩石地球化学学会 成都理工大学

矿物岩石

CSTPCD北大核心
影响因子:0.8
ISSN:1001-6872
年,卷(期):2024.44(1)
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