首页|鄂尔多斯盆地纳岭沟铀矿床铀赋存状态及铀矿物工艺矿物学研究

鄂尔多斯盆地纳岭沟铀矿床铀赋存状态及铀矿物工艺矿物学研究

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铀的赋存状态直接影响在地浸过程中铀的浸出率,通过铀矿物的工艺矿物学特征能反映铀矿物与浸矿剂的接触情况,因此研究矿床中铀赋存状态及铀矿物工艺矿物学特征对地浸开采具有重要意义.本研究运用扫描电镜(SEM)以及综合矿物分析仪(TIMA)等方法对纳岭沟铀矿床铀的赋存状态及铀矿物的工艺矿物学特征(包括铀矿物粒度、解离度、连生矿物占比)进行研究.结果表明:(1)纳岭沟铀矿床铀存在形式以独立铀矿物(主要为轴石)为主,还包括少量含铀矿物(锆石,独居石等)以及吸附态铀.(2)铀矿物粒度基本都处于0~160μm范围内,占比90.07%,其中大部分铀矿物粒度小于50 µm(60.92%),少量(9.93%)的铀矿物粒度大于200 μm.(3)铀矿物与有机质、绿泥石、石英、黑云母、正长石等矿物连生关系密切,其占比分别为21.46%、16.48%、13.76%、11.56%、10.45%,指示铀矿物大部分与矿物连生.本研究有效查明了纳岭沟铀矿床铀矿物的空间嵌布关系,其主要赋存在有机质内部及其表面,除此之外也分布在绿泥石与黑云母的层间裂隙中.因有机质的疏水性以及绿泥石与黑云母的层状结构难以破坏,最终会导致铀的浸出率降低.纳岭沟铀矿床铀赋存状态表明,大部分铀矿物能被浸出,但在实际地浸过程中,部分铀矿物会因难以与溶浸液接触导致铀的浸出率下降.
STUDY ON URANIUM OCCURRENCE STATE AND PROCESS MINERALOGY OF URANIUM MINERALS IN NALINGGOU URANIUM DEPOSIT,ORDOS BASIN
Understanding the occurrence state of uranium is crucial for determining the leaching rate dur-ing ground leaching.The process mineralogy characteristics of uranium minerals provide insights into the interaction between uranium minerals and leaching agents,adding significant value to the study of ore de-posits.This research employs scanning electron microscopy(SEM)and the TESCAN integrated mineral analysis(TIMA)to investigate the occurrence state and process mineralogy characteristics of uranium minerals in the Nalinggou Uranium deposit.The key findings are as follows:(1)Composition of uranium:The uranium in the Nalinggou uranium deposit primarily consists of independent uranium minerals,mainly uranite.A small quantity of uranium-containing minerals,such as zircon and monazite,is also present.Adsorbed uranium is primarily found on the surface of organic matter.(2)Particle size distribution:The particle size of uranium minerals ranges from 0 to 160 μm,with 90.07%falling within this range.The majority of uranium minerals have a particle size less than 50 μm,accounting for 60.92%.A smaller per-centage(9.93%)of uranium minerals have a particle size greater than 200 μm.(3)Association with other minerals:Uranium minerals exhibit close associations with various minerals,including organic matter,chlorite,quartz,biotite,and orthoclase.The proportions of association with these minerals are 21.46%,16.48%,13.76%,11.56%,and 10.45%,respectively.This indicates that the majority of uranium min-erals are closely associated with other minerals,with isolated uranium minerals being relatively rare.This study successfully identifies the spatial distribution relationship of uranium minerals in the Nalinggou ura-nium deposit.Uranium minerals are mainly located within and on the surface of organic matter,as well as distributed in the interlayer cracks between chlorite and biotite.The hydrophobic nature of organic matter and the resistant layered structure of chlorite and biotite contribute to a reduction in the leaching rate of u-ranium during the actual leaching process.While most uranium minerals are leachable,the challenge lies in ensuring their effective contact with the leaching solution to optimize uranium leaching rates.

TIMAProcess mineralogyCO2+O2 ground leachingNalinggou uranium deposit

田增辉、宋昊、范元清、王泽鑫、乔鹏、黄晓东、周靖、张成江、徐争启、谭亚辉

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成都理工大学,四川成都 610059

地学核技术四川省重点实验室,四川成都 610059

中核内蒙古矿业有限公司,内蒙古呼和浩特 010020

核工业北京化工冶金研究院,北京 101149

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TIMA 工艺矿物学 CO2+O2地浸 纳岭沟铀矿床

国家自然科学基金成都理工大学珠峰科学研究计划

U19672072023ZF11413

2024

矿物岩石
四川省矿物岩石地球化学学会 成都理工大学

矿物岩石

CSTPCD北大核心
影响因子:0.8
ISSN:1001-6872
年,卷(期):2024.44(1)
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