首页|内蒙古二连盆地芒来铀矿床岩石矿物学特征及地浸采铀工艺试验

内蒙古二连盆地芒来铀矿床岩石矿物学特征及地浸采铀工艺试验

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可地浸砂岩型铀矿床岩石矿物学特征会直接影响地浸工艺的选择及浸出剂浓度的配置,而前期的室内地浸采铀试验是定性至定量地揭示矿物与浸出剂反应过程最有效的方法之一.本次研究采用X射线荧光光谱分析(XRF)、非水溶液滴定法、电子探针(EPMA)、扫描电镜(SEM)等方法,研究了芒来铀矿床岩石矿物学特征,并开展了室内搅拌浸出和不同酸度注浸试验.结果表明:(1)矿石类型主要为砂岩和砾岩两类,砂岩类矿石以长石岩屑砂岩为主,碎屑物成分中石英平均含量53.60%、长石平均含量20.10%,岩屑平均含量10.40%,重矿物总量一般小于1%,具有近源特征,成分成熟度低.(2)矿石中的黏土矿物以杂基形式存在,砂岩矿石黏土矿物含量均值为14.30%,砾岩矿石的黏土含量均值为12.00%,主要以伊蒙混层和伊利石为主.(3)碳酸盐总体含量很低,围岩碳酸盐平均含量0.41%,矿石碳酸盐平均含量0.48%.(4)铀的赋存状态主要为吸附态铀和铀矿物两种,铀矿物主要为沥青铀矿和磷钙铀矿及少量的铀石.(5)搅拌浸出和不同酸度注浸试验表明矿石中耗酸物资含量低,搅拌浸出试验采用浓度为10 g/L的H2SO4浸出时,浸出率为81.50%,液固体积质量比为1.76 L/kg,未发生堵塞现象,每吨矿耗酸18.41 kg,综合效果及经济效益可达到最好.本研究通过研究芒来铀矿床岩矿物学特征,认为适宜采用酸法浸出工艺,推荐现场地浸试验配液硫酸质量浓度为10 g/L,为后期扩大试验及开发实践提供了重要的依据,对推动二连盆地古河谷砂岩型铀矿床地浸采铀技术方法的理论创新与实践具有重要意义.
PETROLOGY AND MINERALOGY OF IN-SITU LEACHING URANIUM PROCESS TEST OF THE MANGLAI URANIUM DEPOSIT IN ERLIAN BASIN,INNER MONGOLIA
The petrology and mineralogy of leachable sandstone-type uranium deposits play a crucial role in selecting the in-situ leaching process and determining the concentration of leaching agents.Conducting in-situ leaching uranium tests proves to be one of the most effective methods for qualitatively and quantita-tively understanding the reaction processes between minerals and leaching agents.In this study,various methods,including X-ray fluorescence spectrometry(XRF),non-aqueous titration,electron probe micro-analysis(EPMA),and scanning electron microscopy(SEM),were employed to explore the mineralogical features of rocks in the Manglai uranium deposit.Agitation leaching tests and different acidity injection leaching tests were conducted.The findings are as follows:1.The ore-related rocks predominantly consist of sandstone and conglomerate,with feldspar lithic sandstone being prevalent in the sandstone ore.The sandstone composition includes an average quartz content of 53.60%,an average feldspar content of 20.10%,and an average debris content of 10.40%.Heavy minerals are generally less than 1%,indicating characteristics of proximity to the source and low compositional maturity.2.Clay minerals in the ore are present as matrix,with an average content of 14.30%in sandstone ore and 12.00%in conglomerate ore.Mainly composed of illite-montmorillonite mixed layers and illite.3.The carbonate content is very low,with an average of 0.41%in surrounding rocks and 0.48%in ore.4.Uranium occurs primarily as ad-sorbed uranium and uranium minerals,with pitchblende,uraninite,and a small amount of uranium stone being the main uranium minerals.The occurrence forms include gel-like or blocky pitchblende around and within pyrite fractures,worm-like structures of phosphocalcic uranium on clay minerals and around pyrite,and gel-like and small particle forms of coffinite around quartz and within pyrite fractures.5.Stirring leac-hing and different acidity injection leaching tests reveal low acid-consuming material content in the ore.U-sing H2SO4 with a concentration of 10 g/L in the stirring leaching test achieves a leaching rate of 81.50%,without blockage and enhancing economic benefits.Based on this study,the acid leaching process is deemed suitable for the Manglai uranium deposit,and a recommended sulfuric acid concentration of 10 g/L in field leaching tests provides a vital foundation for subsequent expansion tests and practical devel-opment.This research contributes significantly to advancing the theoretical and practical aspects of in-situ leaching uranium technology in the ancient valley sandstone-type uranium deposit of the Erlian Basin.

ManglaiSandstone-type uranium depositsrock mineralogyIn-situ leaching uranium process test

乔鹏、熊盛青、葛良全、阳奕汉、宋昊、张传飞、王如意、任晓平、周意如、于慧杰

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成都理工大学,四川成都 610059

中核内蒙古矿业有限公司,内蒙古呼和浩特 010020

中国自然资源航空物探遥感中心,北京 100083

地学核技术四川省重点实验室,四川成都 610059

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芒来 砂岩型铀矿 岩石矿物学 地浸采铀工艺试验

国家自然科学基金中核集团集中研发项目

U1967207

2024

矿物岩石
四川省矿物岩石地球化学学会 成都理工大学

矿物岩石

CSTPCD北大核心
影响因子:0.8
ISSN:1001-6872
年,卷(期):2024.44(1)
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