矿业安全与环保2024,Vol.51Issue(4) :146-155.DOI:10.19835/j.issn.1008-4495.20240131

大宗煤基固废膏体充填材料少水化配比优化研究

Study on the optimization of proportion parameters for bulk coal-based solid waste low-water filling material

陈登红 秦海月 李超 陈冉
矿业安全与环保2024,Vol.51Issue(4) :146-155.DOI:10.19835/j.issn.1008-4495.20240131

大宗煤基固废膏体充填材料少水化配比优化研究

Study on the optimization of proportion parameters for bulk coal-based solid waste low-water filling material

陈登红 1秦海月 2李超 2陈冉2
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作者信息

  • 1. 安徽理工大学 矿业工程学院,安徽 淮南 232001;合肥综合性国家科学中心能源研究院(安徽省能源实验室),安徽 合肥 230031;深部煤炭安全开采与环境保护全国重点实验室,安徽 淮南 232001
  • 2. 安徽理工大学 矿业工程学院,安徽 淮南 232001
  • 折叠

摘要

为解决西部采煤区固废多、处理难的问题,以宁东矿区的脱硫石膏、粉煤灰、水泥为主要原料,对原料的微观形态及少水配比的煤基固废膏体充填材料的成分进行分析,以初期流动性、脱模后7 d和28 d的抗压强度为指标进行充填材料配比优化.设计了 3 因素 3 水平 17 组配比方案,建立响应面回归模型,分析单因素及多因素交互作用对少水充填材料强度和流动性的影响.研究结果表明,粉煤灰与水泥质量比是影响少水充填材料强度的重要因素,料浆质量分数是影响少水充填材料流动性的重要因素.少水配比的煤基固废膏体充填材料的最优配合比:脱硫石膏质量分数 53%,粉煤灰与水泥质量比2∶1,料浆质量分数 74%.波速与强度的响应关系表明,可以利用充填体的波速来预测其强度.

Abstract

To explore the solution to the problems of water shortage and multi-solid waste treatment in the western coal mining area,the desulfurization gypsum,fly ash and cement in Ningdong mining area were selected as the main raw materials.The micro-morphology of the raw materials and the composition after less water ratio were analyzed.The initial fluidity and the strength of 7 d and 28 d after demoulding were used as indicators to optimize the ratio.The scheme of 3 factors 3 levels and 17 combinations was designed.A response surface regression model was established to analyze the effects of single factor and multi-factor interaction on the strength and fluidity of low-water filling materials.The results show that the mass ratio of fly ash to cement is an important factor affecting the strength.The mass fraction of slurry is an important factor affecting the fluidity.The optimal mix ratio is desulfurization gypsum mass fraction 53%,fly ash and cement mass ratio 2∶1,slurry mass fraction 74%.The relationship between wave velocity and strength shows that the wave velocity of the filling body could be used to predict the strength.

关键词

煤基固废/少水充填/膏体充填材料/响应面法/水化机理

Key words

coal-based solid waste/low-water filling/paste filling material/response surface methodology/hydration mechanism

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基金项目

国家自然科学基金重点项目(52130402)

智能采矿工程新建专业质量提升项目(2022xjzlts008)

省级研究生专业学位教学案例库项目(2022zyxwjxalk087)

出版年

2024
矿业安全与环保
中煤科工集团重庆研究院,国家煤矿安全技术工程研究中心

矿业安全与环保

CSTPCD北大核心
影响因子:0.987
ISSN:1008-4495
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