矿冶工程2024,Vol.44Issue(1) :105-110.DOI:10.3969/j.issn.0253-6099.2024.01.023

MPTS改性高岭土吸附剂的制备及其吸附性能研究

Preparation of MPTS-Modified Kaolin Adsorbent and Its Adsorption Properties

谢雪珍 胡杨玲 叶有明 曾军
矿冶工程2024,Vol.44Issue(1) :105-110.DOI:10.3969/j.issn.0253-6099.2024.01.023

MPTS改性高岭土吸附剂的制备及其吸附性能研究

Preparation of MPTS-Modified Kaolin Adsorbent and Its Adsorption Properties

谢雪珍 1胡杨玲 1叶有明 1曾军1
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作者信息

  • 1. 广西科技师范学院,广西来宾 546199
  • 折叠

摘要

为了处理含电镀络合铜废水,以3-巯丙基三甲氧基硅烷(MPTS)为改性剂,对高岭土进行改性,制备了改性高岭土吸附剂,并研究了其对柠檬酸络合铜(E330-Cu)的吸附效果.适宜的高岭土改性条件为:MPTS相对高岭土用量为0.04 mL/g、改性温度50℃、改性时间6h.改性高岭土吸附剂对E330-Cu适宜的吸附条件为:E330-Cu初始浓度5 mg/L、吸附剂相对用量15 g/L、pH值4.5、吸附时间35 min、吸附温度35 ℃,此时吸附率达到92.50%.吸附过程满足Langmuir等温吸附模型和准二级动力学模型.吸附剂至少可使用3次,处理后废水可达到国家一级排放标准.研究结果可为含电镀络合铜废水的处理提供有力支撑.

Abstract

In order to process copper complex wastewater from electroplating industry,a kind of kaolin was modified by using a modifier of 3-mercaptopropyl trimethoxysilane(MPTS)to be as an adsorbent,and its adsorption of E330-Cu was then studied.It is found that kaolin shall be properly modified at 50 ℃ for 6 hours with the modifier MPTS at an amount of 0.04 mL/g,which is then adopted as an adsorbent for E330-Cu.After 35 min-adsorption at 35 ℃,with E330-Cu at an initial concentration of 5 mg/L,adsorbent at an amount of 15 g/L,and pH value of 4.5,the final adsorption rate can reach 92.50%.It is shown that the adsorption process follows Langmuir isothermal adsorption model and quasi-second-order kinetic model.This kind of adsorbent can be repeatedly used for at least 3 times,and the wastewater after processing can meet the national class Ⅰ discharge standard.This research can provide reference for the treatment of copper-containing complex wastewater from electroplating industry.

关键词

废水处理/吸附剂/3-巯丙基三甲氧基硅烷/改性高岭土/电镀废水/吸附

Key words

wastewater treatment/adsorbent/3-mercaptopropyl trimethoxysilane(MPTS)/kaolin modification/electroplating wastewater/adsorption

引用本文复制引用

基金项目

广西无机材料绿色制备与应用重点实验室项目(桂科AD20297139)

来宾市金属材料加工与清洁生产重点实验室项目(来科能193301)

广西科技师范学院青年科研创新团队项目(GXKS2020QNTD04)

出版年

2024
矿冶工程
长沙矿冶研究院有限责任公司 中国金属学会

矿冶工程

CSTPCD北大核心
影响因子:1.137
ISSN:0253-6099
参考文献量17
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