矿冶工程2024,Vol.44Issue(1) :129-133.DOI:10.3969/j.issn.0253-6099.2024.01.028

表面包覆碳层孔隙对石墨负极材料倍率性能的影响

Effects of Pores in Surface-Coated Carbon Layer on Rate Performance of Graphite Cathode Materials

刘云峰 谭婷 杨乐之 银华杰 梁帆 王双 罗磊 涂飞跃
矿冶工程2024,Vol.44Issue(1) :129-133.DOI:10.3969/j.issn.0253-6099.2024.01.028

表面包覆碳层孔隙对石墨负极材料倍率性能的影响

Effects of Pores in Surface-Coated Carbon Layer on Rate Performance of Graphite Cathode Materials

刘云峰 1谭婷 1杨乐之 1银华杰 1梁帆 1王双 1罗磊 1涂飞跃1
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作者信息

  • 1. 长沙矿冶研究院有限责任公司,湖南长沙 410012
  • 折叠

摘要

为了研究表面包覆碳层孔隙对石墨负极材料倍率性能的影响,引入少量硼酸,在包覆沥青软化阶段形成硼酸气化逸出效应,再通过碳化工艺在天然石墨尾料表面形成具有一定孔隙的包覆碳层,得到具有不同比例孔隙的石墨负极材料.结果表明,硼酸在材料颗粒表面形成了含有孔隙的碳层,其孔隙类型为介孔和大孔;表面碳层中的介孔比例越高,碳层LC中形成Li+的扩散通道数量越多,Li+的扩散阻抗越低,材料倍率性能及循环性能得以改善.

Abstract

In order to study the effects of pores in surface-coated carbon layer on the rate performance of graphite cathode materials,a small amount of boric acid was added to generate gasification and effusion effect of boric acid during the softening stage of the coated asphalt.Then,a carbon layer with certain pores was formed on the surface of natural graphite tailings through carbonization,and graphite cathode materials with various proportions of pores were obtained.The results show that boric acid forms a carbon layer on the surface of particles containing mesoporous and macroporous pores.A higher proportion of mesopores in the surface carbon layer leads to more diffusion channels for Li+in the carbon layer LC,and lower diffusion impedance of Li+.In that case,the rate performance and cycling performance of the material are enhanced.

关键词

锂离子电池/石墨负极/天然石墨尾料/硼酸/沥青/碳层结构/碳化工艺/负极材料/循环性能

Key words

lithium-ion batteries/graphite cathode/natural graphite tailings/boric acid/asphalt/carbon layer structure/carbonization process/cathode material/cyclic performance

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基金项目

国家重点研发计划(2020YFC1909604)

出版年

2024
矿冶工程
长沙矿冶研究院有限责任公司 中国金属学会

矿冶工程

CSTPCD北大核心
影响因子:1.137
ISSN:0253-6099
参考文献量12
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