矿冶工程2024,Vol.44Issue(1) :161-165.DOI:10.3969/j.issn.0253-6099.2024.01.035

固载离子液体材料的制备及其对水环境中汞离子的去除

Preparation of Immobilized Ionic Liquid and Removal of Mercury Ions in Water

邹文清 何松珉
矿冶工程2024,Vol.44Issue(1) :161-165.DOI:10.3969/j.issn.0253-6099.2024.01.035

固载离子液体材料的制备及其对水环境中汞离子的去除

Preparation of Immobilized Ionic Liquid and Removal of Mercury Ions in Water

邹文清 1何松珉1
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作者信息

  • 1. 海南绿境高科环保有限公司,海南海口 570311
  • 折叠

摘要

采用浸渍法将咪唑基离子液体固载于磁性纳米颗粒表面,制备得到固载离子液体复合材料Fe3O4@SiO2@IL.采用Fe3O4@SiO2@IL去除水环境中的Hg2+,研究了 pH值、吸附时间、吸附剂用量及Hg2+初始浓度对Hg2+去除率的影响.结果表明,Fe3O4@SiO2@IL适用pH值范围宽,pH=7.2~9.5时,Hg2+去除率达99.1%以上.Fe3O4@SiO2@IL对Hg2+的吸附速度快,只需90 min即可达到吸附平衡.对于25 mL浓度2 μg/mL的Hg2+溶液,加入20 mg吸附剂即可基本去除其中Hg2+,Fe3O4@SiO2@IL的吸附等温线研究结果表明,吸附剂对Hg2+的饱和吸附量为548.37 mg/g.

Abstract

Fe3O4@SiO2@IL was prepared by immobilizing imidazole based ionic liquids on the surface of magnetic nanoparticles with impregnation method,and was then used to remove Hg2+in the water.The effects of pH value,adsorption time,and adsorbent dosage on the Hg2+removal rate were investigated.The results show that Fe3O4@SiO2@IL can have a wide application,and Hg2+removal rate can exceed 99.1%with pH of 7.2-9.5.Fe3O4@SiO2@IL presents a high rate of Hg2+adsorption,and the adsorption can reach equilibrium within 90 minutes.For 25 mL Hg2+solution with a concentration of 2 μg/mL,Hg2+can be completely removed by adding 20 mg of adsorbent.The adsorption isotherms of Fe3O4@SiO2@IL indicate that the saturated adsorption capacity of the adsorbent for Hg2+is 548.37 mg/g.

关键词

固载离子液体/磁性纳米颗粒/咪唑/汞离子/吸附/静电作用

Key words

immobilized ionic liquid/magnetic nanoparticles/imidazole/mercury ions/adsorption/electrostatic interaction

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出版年

2024
矿冶工程
长沙矿冶研究院有限责任公司 中国金属学会

矿冶工程

CSTPCD北大核心
影响因子:1.137
ISSN:0253-6099
参考文献量16
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