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磷矿配炭球团高温固结工艺研究

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为解决窑法磷酸工艺中回转窑结圈问题,提出一种球团高温固结工艺,考察了黏结剂种类、固结温度、固结时间对磷矿球团强度及其还原性的影响.结果表明,固结温度 800℃以上,采用膨润土为黏结剂,球团抗压强度和落下强度明显高于腐殖酸钠为黏结剂的球团.在配碳量为理论用量的 1.4 倍、CaO与SiO2 物质的量比 0.35、膨润土添加量为总物料量的 1.5%、固结温度 1000℃、固结时间 30 min条件下,球团抗压强度和落下强度分别为 345.36 N和 33.50 次.
Preliminary Study on High-Temperature Consolidation Conditions for Carbon-Bearing Phosphate Ore Pellets
In order to avoid formation of material ring in a rotary kiln caused by kiln phosphoric acid process,a technique of high-temperature consolidation of pellets was proposed,and the effects of types of binder,temperature and time of consolidation on the strength and reducibility of phosphate ore pellets were investigated.The results show that consolidation at a temperature over 800℃with bentonite as binder can lead to the pellets with compressive strength and drop numbers obviously higher than those with sodium humate as the binder.With an addition of carbon at 1.4 times of the theoretical amount,CaO and SiO2 at a molar ratio of 0.35,an addition of bentonite at an amount of 1.5%of the total material weight,consolidation at 1 000℃for 30 min results in the produced pellets with compressive strength of 345.36 N and drop numbers of 33.50.

phosphoric acidcarbon-bearing pellethigh-temperature consolidationkiln phosphoric acidmaterial ring in a rotary kilnpellet strengthbinderbentonitesodium humate

魏世发、马彪、任国兴

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长沙矿冶研究院有限责任公司,湖南 长沙 410012

郑州大学 中原关键金属实验室,河南 郑州 450001

磷酸 配炭球团 高温固结 窑法磷酸 回转窑结圈 球团强度 黏结剂 膨润土 腐殖酸钠

国家重点研发计划

2018YFC1900204

2024

矿冶工程
长沙矿冶研究院有限责任公司 中国金属学会

矿冶工程

CSTPCD北大核心
影响因子:1.137
ISSN:0253-6099
年,卷(期):2024.44(2)
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