首页|枣树枝改性生物炭对水溶液中锌离子的吸附性能研究

枣树枝改性生物炭对水溶液中锌离子的吸附性能研究

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通过水热碳化枣树枝生成水热炭,以氯化锌为活化剂对水热炭进行活化,得到枣树枝改性生物炭,所得生物炭表面具有丰富的孔结构及高度芳香化结构.以枣树枝改性生物炭为吸附剂吸附溶液中Zn2+,在吸附时间 80 min、溶液pH=9、改性生物炭投加量 700 mg/L、反应温度 55℃、Zn2+初始浓度 30 mg/L条件下,Zn2+去除率达到 99%以上;吸附过程与Freundlich吸附模型拟合度高,表明改性生物炭对Zn2+的吸附过程为多层分子吸附;改性生物炭经 5 次循环吸附与解吸后,对Zn2+去除率仍在 97%以上.
Adsorption of Zinc Ions in Aqueous Solution by Modified Biochar from Jujube Branch
Hydrothermal carbon generated by hydrothermal carbonization of waste jujube branches was activated with zinc chloride as an activator,and a kind of modified biochar was prepared with highly porous and aromatic structure on its surface,which was then used to adsorb Zn2+in aqueous solution.It is shown that for the solution with pH of 9 and initial Zn2+concentration of 30 mg/L,after 80 min adsorption at a temperature of 55 ℃ by adding 700 mg/L modified biochar,the removal rate of Zn2+therein exceeds 99%.The adsorption process is well-fitted to the Freundlich adsorption model,indicating that the adsorption process with the modified biochar is a multilayer molecular adsorption.The removal rate of Zn2+by the modified biochar,after 5 cycles of adsorption and desorption,can still remain over 97%.

wastewater treatmentwastewater from metallurgical processing of zincjujube branchesbiomassbiocharadsorbentzinc chloridezinc ion

陈冬素、陈亮、阎丽

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湖南省环境保护科学研究院,湖南 长沙 410004

废水处理 锌冶炼废水 枣树枝 生物质 生物炭 吸附剂 氯化锌 锌离子

湖南省科技创新计划项目

2021RC5030

2024

矿冶工程
长沙矿冶研究院有限责任公司 中国金属学会

矿冶工程

CSTPCD北大核心
影响因子:1.137
ISSN:0253-6099
年,卷(期):2024.44(3)
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