矿冶工程2024,Vol.44Issue(4) :24-30.DOI:10.3969/j.issn.0253-6099.2024.04.005

LiMn0.6Fe0.4PO4/C正极材料的制备与电化学性能研究

Synthesis and Electrochemical Performance of LiMn0.6Fe0.4PO4/C Cathode Materials

丁伦涛 赵鹏 周春仙 王德志 吴壮志 李雪豹 周友元
矿冶工程2024,Vol.44Issue(4) :24-30.DOI:10.3969/j.issn.0253-6099.2024.04.005

LiMn0.6Fe0.4PO4/C正极材料的制备与电化学性能研究

Synthesis and Electrochemical Performance of LiMn0.6Fe0.4PO4/C Cathode Materials

丁伦涛 1赵鹏 2周春仙 2王德志 1吴壮志 1李雪豹 1周友元2
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作者信息

  • 1. 中南大学材料科学与工程学院,湖南长沙 410083
  • 2. 湖南长远锂科股份有限公司,湖南长沙 410221
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摘要

采用共沉淀法和固相烧结法制备了一种杂质少、物相分布均匀、电化学性能优良的LiMn0.6Fe0.4PO4/C(LMFP)复合材料.结果表明,该方法在脱去NH4+和H2O的同时,抑制了 Mn2P2O7物相的产生,提高了 LMFP的锂离子扩散速率.由LiMn0.6Fe0.4PO4/C组装的锂离子电池展示了优异的电化学性能,1C下首次放电比容量145.5 mAh/g;5C下首次放电比容量111.9 mAh/g.该工艺简单、成本低,适合工业化生产,为设计高性能的商业化锂离子电池正极材料提供了可行性方案.

Abstract

LiMn0.6Fe0.4PO4/C(LMFP)composite synthesized by a combined process of co-precipitation and solid-phase sintering not only has low impurity content,uniform phase distribution,but also exhibits excellent electrochemical performance.It is shown that such process can inhibit the formation of Mn2P2O7 phase and improve the lithium ion diffusion rate of LMFP,while removing NH4+and H2O.The Li-ion batteries assembled with LiMn0.6Fe0.4PO4/C exhibit excellent electrochemical performance,showing initial specific discharge capacity of 145.5 mAh/g at 1C and 111.9 mAh/g at 5C.It is concluded that this process,being simple and cost-effective,is suitable for industrial production.Such study provides a feasible scheme in designing cathode materials for commercialized high-performance Li-ion batteries.

关键词

锂离子电池/磷酸铁锂/磷酸锰铁锂/正极材料/LiMn0.6Fe0.4PO4/前驱体/煅烧/碳包覆/工业化

Key words

Li-ion battery/LiFePO4/LiMnxFe1-xPO4/cathode material/LiMn0.6Fe0.4PO4/precursor/calcination/carbon coating/industrialization

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基金项目

长沙市科技重大专项(kh2401022)

出版年

2024
矿冶工程
长沙矿冶研究院有限责任公司 中国金属学会

矿冶工程

CSTPCD北大核心
影响因子:1.137
ISSN:0253-6099
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