首页|3D花状VO2(B)正极材料的制备与电化学性能研究

3D花状VO2(B)正极材料的制备与电化学性能研究

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以五氧化二钒和柠檬酸为原料,采用水热反应法制备了具有大比表面积和优异结构稳定性的3D花状VO2(B)电极材料.采用X射线衍射、扫描电子显微镜、透射电子显微镜等对VO2(B)晶体结构和形貌进行了表征,通过恒流充放电、循环伏安法等对VO2(B)电极材料的电化学性能进行了测试.结果表明:电流密度0.1 A/g下,3D花状VO2(B)电极材料的首次放电比容量达227 mAh/g;1 A/g高电流密度下,初始放电比容量仍达151 mAh/g,300次充放电循环后的容量保持率为79.6%,该电极材料表现出良好的倍率性能.
Preparation and Electrochemical Properties of 3D Flower-Like VO2(B)Cathode Material
With vanadium pentoxide and citric acid as raw materials,a kind of 3D flower-like VO2(B)electrode material with large specific surface area and excellent structural stability was prepared by adopting hydrothermal synthesis.The crystal structure and morphology of the VO2(B)electrode material were characterized by X-ray diffraction,scanning electron microscope,and transmission electron microscope,and the electrochemical properties of VO2(B)electrode material were measured by constant current charge and discharge,as well as cyclic voltammetry.The results show that the first specific dischage capacity of 3D flower-like VO2(B)electrode material is 227 mAh/g at a current density of 0.1 A/g.It delivers the first specific discharge capacity of 151 mAh/g at a high current density of 1 A/g,and retains 79.6%of this capacity after 300 charge-discharge cycles,exhibiting a good rate performance.

lithium-ion batteryvanadium dioxidecathode materialcycling performance3D flower-like structurevanadium electrode material

孔孟、郭攀、陈阳阳

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河南物流职业学院智能制造与交通学院,河南郑州 450000

郑州大学力学与安全工程学院,河南郑州 450000

许昌电气职业学院机电工程系,河南许昌 461000

锂离子电池 二氧化钒 正极材料 循环性能 3D花状结构 钒电极材料

2024

矿冶工程
长沙矿冶研究院有限责任公司 中国金属学会

矿冶工程

CSTPCD北大核心
影响因子:1.137
ISSN:0253-6099
年,卷(期):2024.44(4)