首页|高炉渣提取硅制备高性能锂离子电池硅碳负极材料的研究

高炉渣提取硅制备高性能锂离子电池硅碳负极材料的研究

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以高炉渣中提取的硅材料BFSi为硅源、聚丙烯腈(PAN)为碳源制备锂离子电池硅碳负极材料,研究了硅与聚丙烯腈的配比对BFSi@C材料电化学性能的影响.结果表明:BFSi与PAN质量比3∶1时制备的BFSi@C样品在0.5 A/g电流密度下初始充电比容量为1 884.99 mAh/g,经过100次循环后,充电比容量仍有1 509.32 mAh/g,容量保持率为80.07%;在高电流密度下,BFSi@C材料表现出优异的倍率性能.与商业硅材料相比,BFSi@C具有更高的循环容量和更好的倍率性能,在5 A/g电流密度下比容量高达 538.31 mAh/g.
Synthesis of High-Performance Silicon-Carbon Anode Materials with Silicon Extracted from Blast Furnace Slag for Lithium-Ion Batteries
With silicon material(BFSi)extracted from blast furnace slag as silicon source and polyacrylonitrile(PAN)as carbon source,a kind of silicon-carbon anode material for lithium-ion batteries was synthesized.And the influence of ratio of silicon to polyacrylonitrile on the BFSi@C material was investigated.Results show that BFSi@C synthesized with BFSi and PAN in a mass ratio of 3:1 delivers an initial charge capacity of 1 884.99 mAh/g at a curr-ent density of 0.5 A/g.After 100 cycles,it still delivers a specific charge capacity of 1 509.32 mAh/g,with a capacity retention rate of 80.07%.Moreover,it presents excellent rate performance at high current densities.Compared with commercial silicon materials,BFSi@C demonstrates higher cycle capacity and superior rate performance,delivering a specific capacity up to 538.31 mAh/g at a current density of 5 A/g.

blast furnace slagsilicon materialpolyacrylonitrilelithium-ion batterysilicon-carbon anodeelectrochemical performance

刘思名、赵俊楷、孟必成、张豪、田文鑫、俞娟

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西安建筑科技大学冶金工程学院,陕西西安 710055

高炉渣 硅材料 聚丙烯腈 锂离子电池 硅碳负极 电化学性能

国家自然科学基金陕西省自然科学基础研究计划

523743582023-JC-QN-0436

2024

矿冶工程
长沙矿冶研究院有限责任公司 中国金属学会

矿冶工程

CSTPCD北大核心
影响因子:1.137
ISSN:0253-6099
年,卷(期):2024.44(4)