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三元正极废粉与聚丙烯共热解-水浸选择性提锂研究

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开展了三元正极废粉与聚丙烯型隔膜共热解-水浸选择性提锂试验,并对反应产物进行了表征.结果表明,在聚丙烯用量40%、热解温度550 ℃、热解时间2 h、氩气流速200 mL/min条件下共热解,热解产物水浸,锂浸出率为87.92%.锂损失的主要原因是共热解过程中形成了不溶于水的锂钴氧化物.
Selective Extraction of Lithium by Co-Pyrolysis of Spent NCM Cathode Powder and Polypropylene Followed by Water Leaching
An experiment was conducted on selective extraction of lithium by co-pyrolysis of spent NCM cathode powder and polypropylene followed by water leaching,and the obtained pyrolysis products were characterized.In the experiment,co-pyrolysis of NCM cathode powder with 40%polypropylene ran at 550 ℃ for 2 h,with argon flow rate at 200 mL/min,and then the obtained pyrolysis product was subjected to water leaching,resulting in the lithium leaching rate of 87.92%.It is found that lithium loss is mainly attributed to the formation of water-insoluble lithium cobalt oxide during co-pyrolysis.

spent lithium-ion batteryNCM cathode powderpyrolysis reductionlithiumpolypropylenewater leaching

田彤麟、任国兴、郭巍巍、肖松文

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郑州大学中原关键金属实验室,河南郑州 450001

河南鑫安利安全科技股份有限公司,河南郑州 450000

废旧锂离子电池 三元正极粉 热解还原 聚丙烯 水浸

郑州大学高层次人才科研启动项目

32340402

2024

矿冶工程
长沙矿冶研究院有限责任公司 中国金属学会

矿冶工程

CSTPCD北大核心
影响因子:1.137
ISSN:0253-6099
年,卷(期):2024.44(4)