Leaching of Metal Elements from Lithium Cobalt Oxide with Dicarboxylic Acid-Based Deep Eutectic Solvent
In order to recover metal elements from the cathode materials of spent Li-ion batteries in an environmentally friendly and efficient way,three deep eutectic solvents(DES)were synthesized with choline chloride as hydrogen bond acceptor,malonic acid,succinic acid and adipate respectively as hydrogen bond donors.Then,Co and Li in the cathode materials of spent Li-ion batteries were leached by adopting these three DESs respectively.The effects of leaching time,liquid-solid ratio and reaction temperature on the leaching rates of Co and Li were explored,and the leaching residues were also characterized in terms of morphology and phase.The leaching mechanism was analyzed by FT-IR spectrum and UV-Vis absorption spectrum.It is shown that the leaching efficiency of metal elements can be enhanced by prolonging leaching time,increasing liquid-solid ratio and temperature.It is found that under the optimal conditions,including leaching time of 300 minutes,liquid-solid ratio of 100 mL/g,and temperature of 110 ℃,malonic acid-based DES,among those three kinds of DESs,can bring better leaching effect,with leaching rates of Co and Li all exceeding 99％.During the leaching of lithium cobalt oxide with those three DESs,Co exists in the form of bivalent in the leaching solution,and the coordination compound is in a tetrahedral structure.
deep eutectic solvent(DES)spent Li-ion batterycathode materialleachinglithium cobalt oxidecobaltlithiumdicarboxylicacidmechanism
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