矿冶工程2024,Vol.44Issue(4) :237-240.DOI:10.3969/j.issn.0253-6099.2024.04.046

赤泥用于酸性含锰废水中锰的净化研究

Purification of Manganese in Manganese-Containing Acidic Wastewater by Red Mud

阎丽 陈冬素
矿冶工程2024,Vol.44Issue(4) :237-240.DOI:10.3969/j.issn.0253-6099.2024.04.046

赤泥用于酸性含锰废水中锰的净化研究

Purification of Manganese in Manganese-Containing Acidic Wastewater by Red Mud

阎丽 1陈冬素1
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作者信息

  • 1. 湖南省环境保护科学研究院,湖南长沙 410004
  • 折叠

摘要

采用还原焙烧-磁选预处理赤泥,得到非磁性物;非磁性物经煅烧、盐酸溶出后加入饱和偏铝酸钠聚合剂聚合后过滤、熟化制备聚合氯化铝(PAC)基液;使用该PAC基液,在沉降时间5 h、PAC基液与废水体积比1∶120、搅拌转速140 r/min、pH值8、反应温度30 ℃、聚丙烯酰胺(PAM)投加量20 mg/L条件下处理含锰酸性废水,处理后液中锰质量浓度由325.3 mg/L降至1.5 mg/L,锰去除率达99.5%,净化后液中锰质量浓度达到国家一级排放标准.

Abstract

Red mud was pre-treated with process of reduction roasting followed by magnetic separation,and the obtained non-magnetic material was calcined and then dissolved in hydrochloric acid.After that,it was filtered after addition of saturated sodium meta-aluminate polymerizing agent,and then matured to prepare polymeric aluminum chloride(PAC)base liquid,which was used in a purification test.With PAC-base liquid and manganese-containing wastewater in a volume ratio of 1∶120,stirring speed of 140 r/min,pH of 8,reaction temperature of 30 ℃,and addition of polyacrylamide(PAM)at an amount of 20 mg/L,the manganese mass concentration in the wastewater reduced from 325.3 mg/L to 1.5 mg/L after 5 hours of settlement,showing manganese removal rate up to 99.5%.It is shown that the manganese mass concentration in the purified liquid can meet class Ⅰ limit in the national discharge standard.

关键词

废水处理//絮凝沉淀法/含锰酸性废水/赤泥/非磁性物/聚合氯化铝/聚丙烯酰胺

Key words

wastewater treatment/manganese/flocculation and precipitation/manganese-containing acidic wastewater/red mud/non-magnetic material/polymeric aluminum chloride(PAC)/polyacrylamide(PAM)

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出版年

2024
矿冶工程
长沙矿冶研究院有限责任公司 中国金属学会

矿冶工程

CSTPCD北大核心
影响因子:1.137
ISSN:0253-6099
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