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方解石在硫酸溶液中表观密度变化规律及其对分选的影响

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研究了酸反应过程中硫酸质量分数、方解石粒径、十二烷基硫酸钠(SDS)添加量和动态流体流速对方解石颗粒表观密度的影响.结果表明:硫酸质量分数 1%时,方解石能稳定在低表观密度状态,且方解石粒径越小,表观密度越低;质量浓度 300 mg/L的SDS能够增强方解石表面疏水性,有效增加CO2 气泡在矿物表面的吸附密度和停留时间,延长方解石颗粒的低表观密度时间;动态流体会加速气泡从方解石表面脱附,不利于酸反应过程中降低方解石表观密度,而SDS处理能显著减小这种不利影响.沉降试验结果表明,酸反应能延长方解石颗粒的沉降时间,创造有利分选条件,能通过重选实现方解石与非碳酸盐矿物的分离.
Change Law of Apparent Density of Calcite in Sulfuric Acid Solution and Its Influence on Separation
The effects of sulfuric acid concentration,calcite particle size,sodium dodecyl sulfate(SDS)dosage and flow rate of dynamic fluid on the apparent density of calcite particles during acid reaction were studied.The results show that when the sulfuric acid concentration is 1%,calcite can sustain at the low apparent density state,and the smaller the calcite sizes,the lower the apparent densities.SDS with a concentration of 300 mg/L can enhance the hydrophobicity of calcite,increase effectively the adsorption density and residence time of CO2 bubbles on calcite,and prolong the duration of low apparent density of calcite.Dynamic fluids may accelerate desorption of gas bubbles from calcite,which is detrimental to the reduction of apparent density of calcite during acid reaction process,but the SDS treatment can significantly reduce this detrimental effect.Settling tests show that acid reaction can prolong the settling time of calcite particles,creating favorable conditions for the separation of calcite and non-carbonate minerals by gravity concentration.

calciteapparent densityCO2 bubblessodium dodecyl sulfate(SDS)dynamic fluidfluoritefluidized bed separationsulfuric acid

赵睿祺、邓荣东、陈佳林、毛志东、魏祥杰、方辰烨、李怀熠

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福州大学 紫金地质与矿业学院,福建 福州 350108

福建省新能源金属绿色提取与高值利用重点实验室,福建 福州 350108

方解石 表观密度 CO2气泡 十二烷基硫酸钠 动态流体 萤石 流态化分选 硫酸

2024

矿冶工程
长沙矿冶研究院有限责任公司 中国金属学会

矿冶工程

CSTPCD北大核心
影响因子:1.137
ISSN:0253-6099
年,卷(期):2024.44(6)