矿冶工程2024,Vol.44Issue(6) :129-133.DOI:10.3969/j.issn.0253-6099.2024.06.028

煤基炭硬模板制备ZnO气敏材料及其对低质量分数乙醇气体的检测

ZnO Synthesized by Hard Templating with Coal-Based Carbon Used as Gas-Sensing Material in Detection of Lowly-Concentrated Ethanol Gas

王驰骋 刘天豪 吴浩宇 袁浩东 陈享享
矿冶工程2024,Vol.44Issue(6) :129-133.DOI:10.3969/j.issn.0253-6099.2024.06.028

煤基炭硬模板制备ZnO气敏材料及其对低质量分数乙醇气体的检测

ZnO Synthesized by Hard Templating with Coal-Based Carbon Used as Gas-Sensing Material in Detection of Lowly-Concentrated Ethanol Gas

王驰骋 1刘天豪 1吴浩宇 1袁浩东 1陈享享1
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作者信息

  • 1. 福州大学 紫金地质与矿业学院,福建 福州 350108;福建省新能源金属绿色提取与高值利用重点实验室,福建 福州 350108
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摘要

以煤基炭为硬模板、醋酸锌为锌源,采用高温焙烧法制备了具有优异晶体结构和孔隙特性的ZnO纳米材料,探究了基于该ZnO材料的气体传感器对乙醇的气敏性能.结果表明:在工作温度 200℃时,ZnO传感器对低质量分数乙醇气体具有较高灵敏度,响应值可达 5.25;ZnO传感器对质量分数为 1×10-5乙醇气体的响应时间和恢复时间分别为 10s和 6 s;ZnO传感器灵敏度与乙醇气体质量分数呈线性关系,检测下限可达 1×10-7;ZnO传感器对醋酸、甲醇、氨水、甲烷等气体的灵敏度较低,对乙醇气体灵敏度高,具有优异的气体检测选择性.

Abstract

With coal-based carbon as a hard template and zinc acetate as zinc source,a kind of ZnO nanomaterial with excellent crystal structure and pore properties was synthesized by adopting high-temperature roasting process.Then,the sensitivity of a gas sensor based on this ZnO nanomaterial to ethanol gas was investigated.The results are shown as follows:such ZnO sensor at 200℃presents higher sensitivity to lowly-concentrated ethanol gas,with a response value of 5.25;the response time and recovery time of the ZnO sensor to the ethanol gas with concentration of 1×10-5are 10 s and 6 s respectively;the ZnO sensor has its sensitivity to ethanol gas in a linear relationship with the concentration of ethanol gas,and can detect the lowest concentration level of 1×10-7;the ZnO sensor has a lower sensitivity to those kinds of gas,including acetic acid,methanol,ammonia and methane.Due to its higher sensitivity to ethanol gas,it is concluded that such sensor presents excellent selectivity in gas detection.

关键词

气体传感器/气敏材料/煤基炭/硬模板法/氧化锌/乙醇/气敏性能

Key words

gas sensor/gas-sensing material/coal-based carbon/hard templating/zinc oxide/ethanol/gas sensitivity

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出版年

2024
矿冶工程
长沙矿冶研究院有限责任公司 中国金属学会

矿冶工程

CSTPCD北大核心
影响因子:1.137
ISSN:0253-6099
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