首页|固废基胶凝材料的微生物辅助胶凝机制研究

固废基胶凝材料的微生物辅助胶凝机制研究

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针对充填采矿中固废基胶凝材料胶凝效果较弱的问题,引入微生物诱导碳酸钙技术(MICP)改善胶凝效果.通过正交试验,对微生物接种量、pH值、试样养护时间的影响做了分析,结合单轴压缩试验证明了MICP技术在充填采矿中的可行性.通过X射线衍射检测、热重分析、扫描电子显微镜测试研究了MICP在充填体中的作用机制.结果表明:微生物辅助胶凝技术在充填采矿中具有可行性,养护3 d和7d的充填体试样平均抗压强度分别提升了25.1%和34.9%;MICP辅助胶凝效果最优的pH值为9,MICP可以促进水化反应,使得充填体中钙钒石等物质含量增多,提高充填体抗压强度;接种微生物后充填体中有碳酸钙晶体生成,晶体填充了充填体缝隙,有效提高了充填体抗压强度.研究成果为类似条件下微生物辅助胶凝的应用提供了理论依据,为MICP技术在充填采矿领域的应用打下了基础.
Mechanism of Microbial-Assisted Gelling of Solid Waste-Based Gelling Materials
Aiming at the problem of weak gelling effect of solid waste-based gelling materials in filling mining,microbial induced calcite precipitation(MICP)was introduced to improve the gelling effect,and the effects of microbial inoculation,pH value,and curing time of the specimens were analyzed through orthogonal tests.Combined with the uniaxial compression test to prove the feasibility of the MICP technology in the filling mining.The mechanism of MICP in the filling body was investigated by X-ray diffraction,thermogravimetric analysis,and scanning electron microscope test.The conclusions are obtained as follows.Microbial-assisted gelling technology is feasible in filling mining,and the average compressive strength of the filling body samples cured for 3 d and 7 d is increased by 25.1%and 34.9%,respectively.The optimal pH value of MICP-assisted gelling is 9.The MICP can promote the hydration reaction,increase the content of ettringite and other substances in the filling body,and improve the compressive strength of the filling body.The research results provide a theoretical basis for the application of microbial-assisted gelling under similar conditions,and lay a foundation for the application of MICP technology in the field of filling mining.

Filling miningSolid waste-based gelling materialMicrobial-assisted gellingMicrobial induced calcite precipitation technology

张文卿、熊博

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山东大学岩土与结构工程研究中心,山东济南 250061

东北大学资源与土木工程学院,辽宁沈阳 110004

充填采矿 固废基胶凝材料 微生物辅助胶凝 微生物诱导碳酸钙技术

2024

矿业研究与开发
长沙矿山研究院有限责任公司 中国有色金属学会

矿业研究与开发

CSTPCD北大核心
影响因子:0.763
ISSN:1005-2763
年,卷(期):2024.44(12)