生物质化学工程2024,Vol.58Issue(2) :39-46.DOI:10.3969/j.issn.1673-5854.2024.02.005

皂化和酯化改性甜菜粕的吸附性能研究

Adsorptive Capacity of Methylene Blue by Saponification and Esterification Modification of Sugar Beet Pulp

张小雨 谢流杰 张艳霞 郭丽君 王玉涛
生物质化学工程2024,Vol.58Issue(2) :39-46.DOI:10.3969/j.issn.1673-5854.2024.02.005

皂化和酯化改性甜菜粕的吸附性能研究

Adsorptive Capacity of Methylene Blue by Saponification and Esterification Modification of Sugar Beet Pulp

张小雨 1谢流杰 1张艳霞 1郭丽君 1王玉涛1
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作者信息

  • 1. 喀什大学生命与地理科学学院,新疆喀什 844000;喀什大学新疆帕米尔高原生物资源与生态重点实验室,新疆喀什 844000
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摘要

为探究甜菜粕(SBP)对亚甲基蓝的最佳吸附工艺条件,本研究对甜菜粕进行皂化改性和脂化改性,分别获得皂化改性甜菜粕(SSBP)和柠檬酸酯化改性甜菜粕(CDSBP),探究两种改性甜菜粕对亚甲基蓝的最佳吸附工艺条件和动力学.结果表明:SSBP最佳吸附工艺条件为亚甲基蓝质量浓度300 mg/L,溶液pH值7,吸附温度60 ℃,吸附时间60 min,吸附量为277.75 mg/g;CDSBP最佳吸附工艺条件为亚甲基蓝质量浓度400 mg/L,溶液pH值8,吸附温度60℃,吸附时间90 min,吸附量最大值为322.4 mg/g,相比较,CDSBP的吸附性能较好.SSBP和CDSBP对亚甲基蓝的吸附过程均符合假二级动力学模型和Langmuir模型,吸附过程主要机制可能为离子交换.SSBP和CDSBP中羟基对提高吸附性能有着重要作用,通过改性处理可以显著增加这些官能团数量,使吸附性能大大提高.

Abstract

To explore the optimum adsorption conditions of methylene blue by sugar beet pulp(SBP),the beet pulp was saponified and modified to obtain saponification modified sugar beet pulp(SSBP)and citric acid esterification modified sugar beet pulp(CDSBP),respectively.The optimum adsorption conditions and kinetics of methylene blue by SSBP and CDSBP were explored.The results showed that the optimum adsorption conditions of SSBP were as follows:the concentration of methylene blue was 300 mg/L,the solution pH value was 7,the adsorption temperature was 60 ℃,the adsorption time was 60 min,and the adsorption capacity was 277.75 mg/g.The optimum adsorption conditions of CDSBP were as follows:the concentration of methylene blue was 400 mg/L,the solution pH value was 8,the adsorption temperature was 60 ℃,the adsorption time was 90 min,and the maximum adsorption capacity was 322.4 mg/g.In contrast,the adsorption performance of CDSBP was better.The adsorption process of methylene blue by SSBP and CDSBP conformed to the pseudo-second-order kinetic model and the Langmuir model,and the main mechanism might be ion exchange.The key chemical groups such as hydroxyl and carbonyl groups in SSBP and CDSBP played an important role in improving the adsorption performance.The number of these functional groups could be significantly increased by modification treatment,so that the adsorption performance was greatly improved.

关键词

甜菜粕/亚甲基蓝/吸附性能/柠檬酸酯化改性/皂化改性

Key words

sugar beet pulp/methylene blue/adsorption property/citric acid ester modification/saponification modification

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基金项目

喀什大学创新团队建设项目(172602)

出版年

2024
生物质化学工程
中国林业科学研究院林产化学工业研究所

生物质化学工程

CSTPCD
影响因子:0.622
ISSN:1673-5854
参考文献量25
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