首页|生物质炭掺杂BiOBr的制备及其光催化性能研究

生物质炭掺杂BiOBr的制备及其光催化性能研究

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以棉浆废液为生物质炭源,采用水热法制备出生物质炭掺杂的BiOBr(C-BiOBr).利用X射线粉末衍射仪、X射线光电子能谱仪、扫描电子显微镜、紫外可见分光光度计等对产物的构效关系进行分析.结果表明:C-BiOBr对罗丹明B溶液的降解率达98.56%,为BiOBr降解率的2.8倍;对盐酸四环素的光降解率达90.4%,为BiOBr降解率的1.6倍.在循环实验中,5次循环后C-BiOBr对罗丹明B的降解依旧能达到88.3%.机理研究结果证明光生空穴和超氧自由基为光催化降解的主要活性物种.所制备的C-BiOBr拥有良好的光催化活性和稳定性,在废水处理中有着潜在的应用前景.
Preparation of Biomass Charcoal Doped BiOBr and Its Photocatalytic Performance
Using cotton pulp waste liquid as a biomass charcoal source,a biomass charcoal doped BiOBr(C-BiOBr)was prepared by a hydrothermal method.The product was analyzed to clarify its structure-function relationship using X-ray powder diffractometer,X-ray photoelectron spectroscope,scanning elec-tron microscope,and ultraviolet-visible spectrophotometer.The results showed that the degradation rate of Rhodamine B solution by C-BiOBr could reach 98.56%,which is 2.8 times that of BiOBr.The photo-degradation rate of tetracycline hydrochloride reached 90.4%,which is 1.6 times that of BiOBr.In the cy-clic experiment,the degradation of Rhodamine B could still reach 88.3%after 5 cycles.Subsequent mech-anism research results proved that photo-generated holes and superoxide radical were the main active sub-stance for photocatalytic degradation.As-synthesized C-BiOBr exhibited good photocatalytic activity and stability,and has potential application prospects in wastewater treatment.

BiOBrbiocharphotocatalysthydrothermal method

顾杰、李双硕、崔天伊、颜菀旻、赵俭波、姜建辉

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新疆兵团南疆化工资源利用工程实验室,塔里木大学化学化工学院,新疆阿拉尔 843300

BiOBr 生物质炭 光催化剂 水热法

2025

聊城大学学报(自然科学版)
聊城大学

聊城大学学报(自然科学版)

影响因子:0.343
ISSN:1672-6634
年,卷(期):2025.38(1)