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磷石膏提质增白净化工艺技术

Purification process technology for improving quality and whitening of phosphogypsum

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磷石膏是湿法磷酸生产的副产物,由于含有磷、氟、有机物等杂质,增加了其综合利用的技术难度,处理不当会造成水污染.在分析磷石膏中主要杂质产生及特性的基础上,提出一种磷石膏提质增白净化工艺技术.将磷石膏再浆后进行浮选净化,去除磷、氟、铁、镁、钠、氯、铝、有机质、泥质及其他有害杂质;过滤后的滤饼与质量分数0.5%的碱性石灰水溶液、固化剂混合反应后,再经陈化处理.所得磷石膏满足GB/T 23456-2018一级石膏以及GB 18599-2020 第Ⅰ类一般工业固体废物标准.
Phosphogypsum is a by-product produced in the production process of wet-process phosphoric acid.Due to the presence of impurities such as phosphorus,fluorine and organic matter,phosphogypsum is difficult to comprehensive utilize,and its improper treatment can cause water pollution.On the basis of analyzing the generation and characteristics of major impurities in phosphogypsum,a process for improving quality,whitening of phosphogypsum is proposed.After repulping of phosphogypsum,flotation purification is carried out to remove phosphorus,fluorine,iron,magnesium,sodium,chlorine,aluminum,organic matter,mud and other harmful impurities from phosphogypsum.The filtered filter cake is mixed with an alkaline lime water solution with a mass fraction of 0.5%and a solidifying agent to react and solidify.The purified phosphogypsum meets the standards of class I gypsum in GB/T 23456-2018 and class I general solid waste standards in GB 18599-2020.

phosphogypsumimprove qualitywhiteningpurificationprocess

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甘肃瓮福化工有限责任公司,甘肃 金昌 737200

磷石膏 提质 增白 净化 工艺

2024

磷肥与复肥
郑州大学 中国磷肥工业协会

磷肥与复肥

CSTPCD
影响因子:0.291
ISSN:1007-6220
年,卷(期):2024.39(3)
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