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热解法合成全氟正丙基乙烯基醚的研究进展

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全氟正丙基乙烯基醚(PPVE)作为重要的氟化工单体,其合成方法主要是热解法.热解法是以六氟环氧丙烷二聚体((HFPO)2)为原料,经过成盐反应和脱羧反应制得PPVE.综述热解法合成PPVE的研究进展,其中直接热解法具有过程简单、反应温度高、副产物种类多等特点;催化热解法具有反应温度较低、选择性较高、操作要求严格等特点,是一种有前景的制备PPVE的方法.
Research progress in the synthesis of PPVE by pyrolysis method
As a critical fluorine chemical monomer,PPVE is primarily synthesized through pyrolysis.This process involves utilizing hexafluoropropylene oxide dimer((HFPO)2)as a raw material,leading to PPVE through a series of reactions including salt formation and decarboxylation.The research progress in the pyrolysis method for synthesizing PPVE is overviewed.The direct pyrolysis method offers a relatively simple process but involves high reaction temperature and yields various by-products;The catalytic pyrolysis method operates at lower temperature,exhibits higher selectivity,and requires strict operation,making it a promising approach for PPVE preparation.

pyrolysis methodperfluoropropyl vinyl ether(PPVE)hexafluoropropylene oxide dimersynthesis

侯江坤、陈伟峰、左岳、王训遒

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郑州大学 化工学院,河南 郑州 450001

浙江巨圣氟化学有限公司,浙江 衢州 324004

热解法 全氟正丙基乙烯基醚 六氟环氧丙烷二聚体 合成

2024

磷肥与复肥
郑州大学 中国磷肥工业协会

磷肥与复肥

CSTPCD
影响因子:0.291
ISSN:1007-6220
年,卷(期):2024.39(6)
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