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含氟二氧化硅粉体中游离氟的固定研究

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含氟二氧化硅粉体废弃物处置不当会存在潜在的环境污染风险,同时造成硅资源的浪费.对含氟二氧化硅粉体中游离氟的固定进行研究,主要探究去离子水、钙离子交换剂用量对含氟二氧化硅粉体悬浮液pH及游离氟固定效果的影响.实验结果表明,在温度 75℃、搅拌转速200 r/min、反应时间30 min、去离子水加入量200 mL、钙离子交换剂用量12g时,含氟二氧化硅粉体悬浮液pH可达6.16;加入钙离子交换剂改性后含氟二氧化硅粉体中游离氟占比明显减少,在白炭黑与防锈颜料体系有着巨大的应用潜力.
Fixation of free-fluorine in fluorine-containing silicon dioxide powder
Improper disposal of fluorine-containing silicon dioxide powder will lead to potential environmental pollution risk and waste of silicon resources.The fixation of free-fluorine in fluorine-containing silicon dioxide powder is studied,and the effect of water and calcium ion exchanger amount on the pH value and fixation effect of fluorine in fluorine-containing silicon dioxide powder solution is mainly investigated.The experimental results show that the pH of the fluorine-containing silicon dioxide powder solution can reach 6.16 when the temperature is 75℃,the stirring speed is 200 r/min,the reaction time is 30 min,and the amount of water and calcium ion exchanger are 200 mL and 12 g.The proportion of free-fluorine in the modified fluorine-containing silicon dioxide powder are 200 mL and significantly reduced,which has great application potential in the white carbon black and anti-rust pigment system.

fluorine-containing silicon dioxide powdersolid wastefluorine fixationcalcium ion exchanger

赵盈、刘松林、王凤霞、李白玉、吴京兴、翟耀、石劲鹏、刘飞、黄鸿

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瓮福(集团)有限责任公司,贵州 贵阳 550000

中低品位磷矿及共伴生资源高效利用国家重点实验室,贵州 贵阳 550016

贵州佳润天泽新材料有限公司,贵州 贵阳 550016

含氟二氧化硅粉体 固体废弃物 氟固定 钙离子交换剂

贵州省科技计划项目贵州省科技计划项目

黔科中引地[2022]4010黔科合支撑[2023]一般407

2024

磷肥与复肥
郑州大学 中国磷肥工业协会

磷肥与复肥

CSTPCD
影响因子:0.291
ISSN:1007-6220
年,卷(期):2024.39(6)
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