首页|电感耦合等离子体原子发射光谱法快速测定湿法磷酸中硫酸根

电感耦合等离子体原子发射光谱法快速测定湿法磷酸中硫酸根

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采用电感耦合等离子体原子发射光谱法(ICP-AES)建立一种快速、准确测定湿法磷酸中硫酸根含量的方法.湿法磷酸样品经硝酸溶解,控制待测溶液酸度,用ICP-AES在180.731 nm处测定湿法磷酸中w(SO42-),方法检出限为0.065 7 μg/mL,相关系数R2为0.999 0,回收率为94.51%~104.61%,相对标准偏差为1.44%,测定结果与重量法吻合.方法快速、简单,准确度高,重现性好.
Rapid determination of sulfate in WPA by ICP-AES method
An inductively coupled plasma atomic emission spectrometry(ICP-AES)method is developed for the rapid and accurate determination of sulfate in WPA.The phosphoric acid samples are dissolved by nitric acid,control the acidity of the solution,the detection limit of the method is 0.065 7 μg/mL at 180.731 nm,the correlation coefficient is 0.999 0,the recovery rate is 94.51%-104.61%,and the relative standard deviation is 1.44%,the results are consist with gravimetric method.This method is rapid and simple,the result has high accuracy and good precision.

wet-process phosphoric acid(WPA)sulfateinductively coupled plasma atomic emission spectroscopy(ICP-AES)

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云南磷化集团有限公司,云南 昆明 650600

湿法磷酸 硫酸根 ICP-AES

2024

磷肥与复肥
郑州大学 中国磷肥工业协会

磷肥与复肥

CSTPCD
影响因子:0.291
ISSN:1007-6220
年,卷(期):2024.39(9)
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