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净化湿法磷酸副产萃余酸脱镁技术研究现状

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随着净化湿法磷酸装置扩产扩能,副产物萃余酸产生量也在逐年增加,但萃余酸因成分复杂、倍半氧化物含量高,难以被高效利用,尤其杂质中的镁离子更是限制了其利用方向.分析萃余酸的组成及镁离子杂质对其利用的影响.对比分析化学沉淀法、pH调节法、膜分离净化法脱镁的应用及优劣势,并针对萃余酸脱镁提出建议.
Research status of technology for removing magnesium from residual acid after purification of wet-process phosphoric acid
With the expansion of production and capacity of purified wet-process phosphoric acid plant,the amount of by-product residual acid is also increasing year by year.However,the residual acid is difficult to efficiently utilize due to its complex composition and high content of sesquioxides,especially the magnesium ions limit its utilization direction.The composition of residual acid and the impact of magnesium ion on its utilization are analyzed.The application,advantages and disadvantages of chemical precipitation method,pH adjustment method and membrane separation purification method for magnesium removal are compared and analyzed,and rational suggestions are proposed for magnesium removal from residual acid.

purification of residual acidmagnesium removalcomparative analysissuggestion

石通杉、杨俊、刘旭、谢娟

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中低品位磷矿及其共伴生资源高效利用国家重点实验室,贵州 贵阳 550014

瓮福(集团)有限责任公司,贵州 贵阳 550001

萃余酸净化 脱镁 对比分析 建议

贵州省科技计划项目

黔科合中引地[2023]004

2024

磷肥与复肥
郑州大学 中国磷肥工业协会

磷肥与复肥

CSTPCD
影响因子:0.291
ISSN:1007-6220
年,卷(期):2024.39(10)
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