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湿法磷酸副产萃余酸的应用和净化研究进展

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湿法磷酸副产萃余酸中残留大量的离子杂质并且黏度高,导致其中富含的大量磷资源应用受限.为提高磷矿资源综合利用率、推动磷化工产业转型升级和绿色可持续发展,梳理萃余酸的应用研究,包括制备磷酸铵、聚磷酸铵、磷酸脲、磷酸二氢钾、三聚磷酸钠、饲料级磷酸氢钙,以及在磷矿浮选中的应用;总结典型的萃余酸净化方法.展望未来萃余酸的增值和高效利用,以及萃余酸的净化研究方向.
Research progress on application and purification of residual acid by product of wet-process phosphoric acid
A large amount of ion impurities in residual acid from wet-process phosphoric acid extraction and its high viscosity limit the application of the abundant phosphorus resources in it.To improve the comprehensive utilization rate of phosphate rock resources,promote the transformation and upgrading,green and sustainable development of the phosphorus chemical industry,the application research of residual acid is sorted out,including the preparation of ammonium phosphate,ammonium polyphosphate,urea phosphate,potassium dihydrogen phosphate,sodium tripolyphosphate,feed grade calcium hydrogen phosphate,and their application in phosphate rock flotation;The typical methods for purifying residual acids are summarized.The value-added and efficient utilization,as well as research directions for the purification of residual acids in the future are looked forward.

wet-process phosphoric acid(WPA)residual acidapplicationpurification

谢波、杨晓健、陈玟霖、胡国涛

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瓮福(集团)有限责任公司,贵州 贵阳 550001

中低品位磷矿及其共伴生资源高效利用国家重点实验室,贵州 贵阳 550014

湿法磷酸 萃余酸 应用 净化

2024

磷肥与复肥
郑州大学 中国磷肥工业协会

磷肥与复肥

CSTPCD
影响因子:0.291
ISSN:1007-6220
年,卷(期):2024.39(11)