首页|溶剂萃取法分离含铝磷酸废液中铝离子的工艺研究

溶剂萃取法分离含铝磷酸废液中铝离子的工艺研究

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针对含有大量铝离子的磷酸蚀刻废液,研发一种溶剂萃取法脱除金属铝离子的工艺,优化了萃取工艺条件.在使用P-15萃取剂、磺化煤油与P-15萃取剂的质量比为2、萃取相比为4、萃取温度60℃、萃取时间30 min条件下进行五级错流萃取,Al2O3萃取率能够达到58.68%,大幅提升了磷酸废液的价值,为未来磷酸废液的净化回收以及高值化利用提供了可行性.
Study on the process of separating aluminum ions from phosphoric acid waste solution containing aluminum by solvent extraction method
A solvent extraction method has been developed to remove aluminum ions from phosphoric acid etching waste solution which contains a large amount of aluminum ions,and the extraction process conditions have been optimized.Under the conditions of using P-15 extractant,sulfonated kerosene and P-15 extractant in a mass ratio of 2,extraction ratio of 4,extraction temperature of 60 ℃,and time of 30 min,a five stage cross flow extraction is carried out,and the extraction rate of aluminum ions can reach 58.68%,greatly improving the value of phosphoric acid waste solution and providing feasibility for the purification,recovery and high-value utilization of phosphoric acid waste solution in the future.

solvent extraction methodphosphoric acid waste solution containing aluminumaluminum ion separation

吕妍鹭、鲜磊、杨林

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四川大学化学工程学院教育部磷资源综合利用与清洁加工工程中心,四川成都 610065

溶剂萃取法 含铝磷酸废液 铝离子分离

2024

磷肥与复肥
郑州大学 中国磷肥工业协会

磷肥与复肥

CSTPCD
影响因子:0.291
ISSN:1007-6220
年,卷(期):2024.39(12)