首页|基于白云石矿采用化学合成法制备硫基钙镁肥料工艺研究及其在苹果上的应用效果

基于白云石矿采用化学合成法制备硫基钙镁肥料工艺研究及其在苹果上的应用效果

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以煅烧白云石矿粉和硫酸为原料,采用化学合成法直接制备硫基钙镁肥料,研究硫酸用量、硫酸浓度、煅烧白云石矿粉细度、反应温度、熟化时间、搅拌转速与时间对化学合成过程钙、镁转化率的影响,并采用X射线衍射仪对产物进行表征.结果表明,最佳的化学合成工艺条件为:硫酸用量为白云石矿粉质量的120%~140%、硫酸w(H2SO4)64%~68%、煅烧白云石矿粉细度0.125~0.150 mm(通过率≥95%)、反应温度(120±5)℃、熟化时间≥150 min、搅拌转速150 r/min、搅拌时间3 min,在此工艺条件下,实现钙、镁转化率达90%以上.田间试验结果表明,在常规施肥的基础上,施硫基钙镁肥料400~500 g/株,苹果的果实品质、产量及经济效益明显提高.
Research on production process of sulfur-based calcium magnesium fertilizer with chemical synthesis method based on dolomite and its application effect on apple
Using calcined dolomite mineral powder and sulfuric acid as raw materials,the sulfur-based calcium magnesium fertilizer is directly prepared by chemical synthesis method.The effects of the amount of sulfuric acid,sulfuric acid concentration,the fineness of calcined dolomite powder,reaction temperature,aging time,stirring rate and time on the conversion rate of calcium and magnesium by chemical synthesis are studied,and the products are characterized by X-ray diffraction.The results show that the optimum parameters of chemical synthesis method are as follow:The dosages of sulfuric acid is 120%-140%,w(H2SO4)of sulfuric acid is 64%-68%,calcined dolomite powder with particle size of 0.125-0.150 mm accounts for ≥95%,the reaction temperature is(120±5)℃,aging time is ≥150 min,stirring rate is 150 r/min and stirring time is 3 min.Under these conditions,the conversion rate of calcium and magnesium is more than 90%.The field application results show that on the basis of conventional fertilization,the treatment applied 400-500 g sulfur-based calcium magnesium fertilizer per plant can significantly improve the fruit quality,yield and economic benefits of apples.

dolomitechemical synthesis methodsulfur-based calcium magnesium fertilizerconversion rate of calcium and magnesiumapplication effect

李红、杨云洪、王新、李长龙、李晓燕、车太龙

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营口菱镁化工集团有限公司,辽宁营口 115100

辽宁省镁素营养专业技术创新中心,辽宁营口 115100

白云石矿 化学合成法 硫基钙镁肥料 钙、镁转化率 应用效果

2024

磷肥与复肥
郑州大学 中国磷肥工业协会

磷肥与复肥

CSTPCD
影响因子:0.291
ISSN:1007-6220
年,卷(期):2024.39(12)