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钙和硫对VD真空脱气精炼过程夹杂物去除的影响

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研究了Ca和S元素对VD真空精炼过程夹杂物去除的作用.Ca含量对夹杂物的去除作用很大,当钢水w(S)=0.012%~0.014%时,低Ca含量有利于夹杂物的去除.钢水w(Ca)=1×10-6时,夹杂物去除率为74.30%;钢水w(Ca)=8×10-6时,夹杂物去除率显著降低至33.95%.原因是Ca元素使得钢液中固态脱氧产物Al2O3-MgO夹杂物转变为液态的钙铝酸盐类夹杂物,不容易上浮去除.当钢水w(Ca)相同时((7~8)×10-6),高S含量有利于夹杂物的去除.钢水w(S)为135 ×10-6和11× 10-6时,对应的夹杂物去除率分别为33.95%和23.71%,原因是高S含量使得夹杂物中的CaS含量增加,从而提高夹杂物熔点.讨论了Ca和S元素的来源,并提出了提高VD过程夹杂物去除率的措施.
Effect of Ca and S on inclusion removal during vacuum degassing refining process
The effect of Ca and S on inclusion removal during vacuum degassing refining process was investigated.The Ca content had a significant effect on inclusion removal.When the S mass fraction was in the range of 0.012%-0.014%,low Ca content was beneficial for inclusion removal.When the Ca mass fraction was 1 × 10-6 in steel,the inclusion removal rate was 74.30%.When the Ca mass fraction was 8 × 10-6 in steel,however,the inclusion removal rate decreased drastically to 33.95%.The reason was that the Ca element transferred the solid deoxidation product Al2O3-MgO inclusions to liquid calcium aluminate inclusions which were not easy to float and remove.When the Ca mass fraction was(7-8)× 10-6 in steel,high S content was beneficial for inclusion removal.When the S mass fraction was 135 × 10-6 and 11 ×10-6 in steel,the corresponding inclusion removal ratios were 33.95%and 23.71%,respectively.The reason was that high S content increased the CaS content in the inclusions,which made the melting point of inclusions increased.The sources of Ca and S elements were discussed,and measures were proposed to improve the inclusion removal ratio during vacuum degassing refining process.

vacuum degassing refininginclusionremove ratiosulfur contentcalcium content

刘建勋、高小勇、卫红、张立峰

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燕山大学机械工程学院,河北秦皇岛 066004

燕山大学材料科学与工程学院,河北秦皇岛 066004

北方工业大学机械与材料工程学院,北京 100114

真空脱气精炼 夹杂物 去除率 硫含量 钙含量

国家自然科学基金国家自然科学基金

U22A2017152274398

2024

炼钢
武汉钢铁(集团)公司 中国金属学会

炼钢

北大核心
影响因子:0.339
ISSN:1002-1043
年,卷(期):2024.40(2)
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