Effect of Ca and S on inclusion removal during vacuum degassing refining process
The effect of Ca and S on inclusion removal during vacuum degassing refining process was investigated.The Ca content had a significant effect on inclusion removal.When the S mass fraction was in the range of 0.012%-0.014%,low Ca content was beneficial for inclusion removal.When the Ca mass fraction was 1 × 10-6 in steel,the inclusion removal rate was 74.30%.When the Ca mass fraction was 8 × 10-6 in steel,however,the inclusion removal rate decreased drastically to 33.95%.The reason was that the Ca element transferred the solid deoxidation product Al2O3-MgO inclusions to liquid calcium aluminate inclusions which were not easy to float and remove.When the Ca mass fraction was(7-8)× 10-6 in steel,high S content was beneficial for inclusion removal.When the S mass fraction was 135 × 10-6 and 11 ×10-6 in steel,the corresponding inclusion removal ratios were 33.95%and 23.71%,respectively.The reason was that high S content increased the CaS content in the inclusions,which made the melting point of inclusions increased.The sources of Ca and S elements were discussed,and measures were proposed to improve the inclusion removal ratio during vacuum degassing refining process.