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超细高岭土结构及热变性的研究

Study on the Structure and Thermal Denaturation of Ultrafine Kaolin

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研究超细高岭土的分子结构和热变性可为其应用研究提供重要的科学依据.试验采用中红外光谱及变温中红外光谱技术,测定了超细高岭土结构主要官能团的光谱数据,试验结果显示:①超细高岭土主要官能团—OH、Si—O、Al—OH的红外吸收峰主要有 4 种振动模式;②温度的升高会加强游离羟基分子间氢键的缔合作用,Si—O吸收峰的频率发生明显红移,其他官能团没有规律性改变.
The study of the molecular structure and thermal denaturation of ultrafine kaolin can provide an important scientific basis for its application re-search.The test employs mid-infrared spectroscopy and variable temperature mid-infrared spectroscopy technology to measure the spectral data of the main functional groups of ultrafine kaolin structure.The test results show that the infrared absorption peaks of the main functional groups of ultrafine kaolin—OH,Si—O,Al—OH mainly have four vibration modes;and the increase in temperature will strengthen the association of hydrogen bonds between free hydroxyl molecules,and the frequency of the Si—O absorption peak will be significantly red-shifted,and there is no regular change in other functional groups.

ultrafine kaolinstructurethermal denaturationmid-infrared spectroscopyvariable temperature mid-infrared spectroscopy

杜林楠、柴嘉欣、赵心怡、刘晴晴、赫士博、于宏伟

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石家庄学院化工学院,河北 石家庄 050035

河北省麻醉药技术创新中心,河北 石家庄 050035

超细高岭土 结构 热变性 中红外光谱 变温中红外光谱

石家庄市麻醉药技术创新中心项目河北省生物制药国际联合中心项目

石科[2019]34号冀科外函[2022]3号

2024

硫磷设计与粉体工程
中国石化集团南京工程有限公司

硫磷设计与粉体工程

影响因子:0.353
ISSN:1009-1904
年,卷(期):2024.181(4)
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