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石墨相氮化碳降解水中氨氮

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利用石墨相氮化碳降解水中氨氮,并对该材料降解氨氮的效果进行考察.探究了在氙灯照射下,不同初始pH以及不同初始氨氮含量条件下对氨氮降解的影响.结果表明:在氙灯照射下,当初始pH=12,初始氨氮含量为7.5 µg时,石墨相氮化碳对氨氮具有良好的降解效果;当初始pH=13时,控制初始氨氮含量为7.5 µg,光催化2 h后,氨氮去除率为95.68%.采用伪一级动力学模型进行研究,石墨相氮化碳在碱性条件下对氨氮有良好的降解速率,可能归因于随着初始pH的增大,溶液中存在更多的OH-和·OH,从而增强光催化效果.
Graphitic phase carbon nitride was used to degrade ammonia nitrogen in water,and the effect of the material in degrading ammonia nitrogen was investigated.Then,the effects of different initial pH and different initial ammonia nitrogen content on ammonia nitrogen degradation under xenon lamp illumination were explored.The results showed that under xenon lamp irradiation,when the initial pH=12 and the initial ammonia nitrogen content was 5µ g,the graphitic phase carbon nitride has a good degradation effect on ammonia nitrogen.When the initial pH=13,the initial mass of ammonia nitrogen was 7.5 µg,and after photocatalysis for 2 h,the removal rate of ammonia nitrogen was 95.68%.Through pseudo-first-order kinetics,it can be seen that graphitic carbon nitride has a good degradation rate of ammonia nitrogen under alkaline conditions.This may be attributed to the presence of more OH-and·OH in the solution as the initial pH increases,thereby enhancing the photocatalytic effect.

photocatalysisgraphitic carbon nitrideammonia nitrogen

翟瑞琪、高玉、于会娟、张英杰、高翠萍、杨荣彬

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大理大学农学与生物科学学院,云南大理 671003

云南省高校微生物生态修复技术重点实验室,云南大理 671003

大理大学工程学院,云南大理 671003

光催化 石墨相氮化碳 氨氮

云南省基础研究计划青年项目云南省科技厅地方本科高校基础研究联合专项面上项目云南省教育厅科学研究基金项目云南省教育厅科学研究基金项目

202201AU070004202101BA070001-0792023Y10492023J0959

2024

环境保护与循环经济
辽宁环境科学研究院 辽宁省环境科学学会

环境保护与循环经济

影响因子:0.424
ISSN:1674-1021
年,卷(期):2024.44(1)
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