首页|不同热解温度和热解时间下污泥基生物炭的理化特性研究

不同热解温度和热解时间下污泥基生物炭的理化特性研究

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为探究微波热解制备的污泥基生物炭的理化特性,以污泥为研究对象,设置5个热解温度和3个热解时间探究热解工况对污泥基生物炭理化特性的影响.结果表明:热解后生物炭中的C百分比降低,污泥基生物炭比表面积最大为55.13 m2/g;污泥基生物炭的TP含量增加,P的保留率最大为91%;生物炭中重金属出现富集现象.对生物炭中重金属进行形态分布分析,发现Cr的F2形态占比由22%降低到11%,Cu的F2形态由11%降低到3%,Zn的F3+F4形态占比由57%增加到83%.重金属的稳定态占比增加,有利于生物炭中重金属的固化.
In order to explore the development law of physical and chemical properties of sludge-based biochar prepared by microwave pyrolysis,5 pyrolysis temperatures and 3 pyrolysis times were set to explore the influence of pyrolysis conditions on physical and chemical properties of sludge-based biochar.The results showed that the percentage of C in biochar decreased after pyrolysis,the specific surface area of sludge-based biochar was up to 55.13 m2/g,the TP content of sludge-based biochar was up to 91%,and the retention rate of phosphorus was up to 91%.Heavy metals were enriched in biochar.The analysis of the form distribution of heavy metals in biochar showed that the F2 state proportion of Cr form decreased from 22%to 11%.The F2 state of Cu decreased from 11%to 3%,and the F3+F4 state of Zn increased from 57%to 83%.The increase of the proportion of heavy metals in the stable state is conducive to the solidification of heavy metals in biochar.

sludge-based biocharheavy metalsphosphoruspyrolysis temperaturepyrolysis time

张媛媛、李彦龙、宋闯、王兰慧、李骁、李润东

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沈阳航空航天大学能源与环境学院,辽宁沈阳 110136

辽宁省铁岭生态环境监测中心,辽宁铁岭 112000

污泥基生物炭 重金属 热解温度 热解时间

2024

环境保护与循环经济
辽宁环境科学研究院 辽宁省环境科学学会

环境保护与循环经济

影响因子:0.424
ISSN:1674-1021
年,卷(期):2024.44(11)