首页|NiOOH/Bi2WO6光阳极的制备与光电化学分解水性能

NiOOH/Bi2WO6光阳极的制备与光电化学分解水性能

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光电化学分解水可将太阳能转化为氢能,是一种具有潜在应用价值的可再生能源利用技术,受到人们的广泛关注.本文采用水热法和电沉积法联合制备了羟基氧化镍/钨酸铋(NiOOH/Bi2WO6)复合光阳极,通过改变助催化剂的担载量对复合光电极整体性能进行优化.最终优化后的NiOOH/Bi2WO6 光阳极的光电流密度达到0.47 mA/cm2,是纯乌酸铋(Bi2WO6)光阳极的 1.7 倍,NiOOH/Bi2WO6 光阳极的单色光-电子转化效率在365 nm波长处达到1.18%.研究结果表明,负载助催化剂能够促进Bi2WO6 光阳极中光生电子与空穴的分离效率,抑制光生电子空穴的表面复合,以提升光阳极的光电化学性能.
Preparation of NiOOH/Bi2WO6 Photoanode and Photoelectrochemical Water Splitting Performance
Photoelectrochemical water splitting can convert solar energy into hydrogen energy,which is a promising renewable energy production technology and has attracted extensive attention.In this paper,NiOOH/Bi2WO6 photoanode was prepared by hydrothermal method and electrodeposition method,and the performance of the composite photoelectrode was optimized by changing the amount of co-catalyst.The photocurrent density of the optimized NiOOH/Bi2WO6 photoanode reaches 0.47 mA/cm2,which is 1.7 times that of the pure Bi2WO6 photoanode.The incident photon-to-electron conversion efficiency of the NiOOH/Bi2WO6 photoanode reaches 1.18%at a wavelength of 365 nm.The research results show that co-catalyst can promote the separation efficiency of photogenerated electrons and holes in the Bi2WO6 photoanode,and inhibit the surface recombination of photogenerated electrons and holes,and enhance the photoelectrochemical performance of the photoelectrode.

photoelectrochemistrybismuth tungstatenickel oxide hydroxide

范晓星、邓运筹、江姗姗、陶然

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辽宁大学 物理学院,辽宁 沈阳 110036

光电化学 钨酸铋 羟基氧化镍

2024

辽宁大学学报(自然科学版)
辽宁大学

辽宁大学学报(自然科学版)

影响因子:0.371
ISSN:1000-5846
年,卷(期):2024.51(4)