辽宁化工2024,Vol.53Issue(1) :18-21.

NiCo-LDH材料的形貌分析与电化学性能研究

Morphological Analysis and Electrochemical Properties of NiCo-LDH Materials

边建宇 杨洋 郑伊民 刘思彤 赵海涛
辽宁化工2024,Vol.53Issue(1) :18-21.

NiCo-LDH材料的形貌分析与电化学性能研究

Morphological Analysis and Electrochemical Properties of NiCo-LDH Materials

边建宇 1杨洋 1郑伊民 1刘思彤 1赵海涛1
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作者信息

  • 1. 沈阳理工大学, 辽宁 沈阳 110159
  • 折叠

摘要

采用一步水热法在泡沫镍上合成镍钴层状双金属氢氧化物(NiCo-LDH)电极材料,用扫描电镜分析电极材料的微观形貌,X 射线衍射仪分析电极材料的物相,并在不同扫描速率以及不同电流密度下NiCo-LDH纳米材料进行了电化学性能测试.结果表明:随着尿素含量的增加,NiCo-LDH的形貌由六角片状、草丛状,最后形成片层上带有针状形貌.扫描速率为 10 mV·s-1时,在CV曲线中可以清晰地看到氧化还原峰.电极在0.30~0.35 V之间的充放电曲线出现对称的充放电平台,说明其充放电容量和充放电时间均较优,该复合材料的电容性能良好.

Abstract

Nickel-cobalt layered bimetal hydroxide(NiCo-LDH)electrodes were synthesized on foamed nickel by one-step hydrothermal method.The morphology of the electrodes was analyzed by scanning electron microscopy,and the phase of the electrodes was analyzed by X-ray diffraction.The electrochemical properties of the NiCo-LDH nanomaterials were tested at different scanning rates and current densities.The results showed that with the increase of urea content,the morphology of NiCo-LDH changed from hexagonal lamellae to grassy tufts,and finally to needle-like lamellae.The redox peak was clearly seen in the CV curve at a scanning rate of 10 mV.s-1.The symmetrical charging and discharging platforms appeared in the charge-discharging curves between 0.30 V and 0.35 V,indicating that both the charging and discharging capacity and the charging and discharging time were excellent,and the composite material had good capacitive performance.

关键词

层状双金属氢氧化物/NiCo-LDH/纳米材料

Key words

Nickel-cobalt layered hydroxide/Compound material/Nanophase materials

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基金项目

大学生创新创业训练计划(202210144010)

沈阳市科技计划项目(22-322-3-18)

出版年

2024
辽宁化工
辽宁省化工学会

辽宁化工

影响因子:0.234
ISSN:1004-0935
参考文献量6
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