辽宁化工2024,Vol.53Issue(1) :26-30.

主客体相互作用实现含氟单体水相聚合诱导自组装

Self-assembly of Fluorinated Monomer Aqueous Phase Induced by Host-guest Interaction

丁柯 丁石宗 韩安迪
辽宁化工2024,Vol.53Issue(1) :26-30.

主客体相互作用实现含氟单体水相聚合诱导自组装

Self-assembly of Fluorinated Monomer Aqueous Phase Induced by Host-guest Interaction

丁柯 1丁石宗 1韩安迪1
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作者信息

  • 1. 北方民族大学, 宁夏 银川 75002
  • 折叠

摘要

论文致力于高浓度高重现性的精准制备含氟组装体,同时将微波辅助用于聚合诱导自组装(PISA),建立微波辅助含氟单体水相PISA新方法.引入随机甲基-β-环糊精(MCD)与含氟疏水单体形成水溶性主客体复合物,在微波辅助下成功制备不同粒径的组装体,通过接触角的测试,证明了含氟微球具有良好的成膜性能和疏水性能,可以用作含氟水性涂料.

Abstract

A new method for microwave-assisted aqueous PISA was established by accurately preparing fluorine-containing assemblies with high concentration and high reproducibility,and at the same time using microwave-assisted polymerization-induced self-assembly(PISA).Random methyl-β-cyclodextrin(MCD)was introduced with fluorine-containing hydrophobic monomers to form water-soluble host-guest complexes,and assemblies with different particle sizes were successfully prepared with microwave assistance.Through the contact angle test,it has been proved that fluorine-containing microspheres have good film-forming properties and hydrophobic properties,and can be used as fluorine-containing waterborne coatings.

关键词

主客体相互作用/RAFT聚合/聚合诱导自组装/含氟组装体

Key words

Host-guest interaction/RAFT polymerization/Polymerization-induced self-assembly/Fluorine-containing assembly

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基金项目

自治区级大学生创新创业训练计划项目(S202211407005)

出版年

2024
辽宁化工
辽宁省化工学会

辽宁化工

影响因子:0.234
ISSN:1004-0935
参考文献量1
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