首页|Cu-20Co-20Cr-20Ni合金在0.5mol·L-1中性NaCl溶液中腐蚀行为研究

Cu-20Co-20Cr-20Ni合金在0.5mol·L-1中性NaCl溶液中腐蚀行为研究

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纳米材料因其自身独特性能而备受关注,从而引发了人们对其进行一系列的研究.采用机械合金化法(MA)和粉末冶金法(PM)制备了纳米尺寸和常规尺寸粉末,通过控制温度和压力等因素,利用真空热压烧结炉将两种不同尺寸的Cu-20Co-20Cr-20Ni粉末热压成块体合金,并利用电化学测试技术研究了它们在0.5 mol·L-1 中性NaCl溶液中的腐蚀行为以及纳米化对其腐蚀行为的影响.结果表明:当Cu-20Co-20Cr-20Ni合金处于 0.5 mol·L-1 NaCl腐蚀溶液中时,纳米尺寸Cu-20Co-20Cr-20Ni合金较相应的常规尺寸合金自腐蚀电位发生正移,电荷传递电阻变大,腐蚀电流密度减小.可见,晶粒细化导致Cu-20Co-20Cr-20Ni合金的耐腐蚀性能增强.
Corrosion Behavior of Cu-20Co-20Cr-20Ni Alloy in 0.5 mol·L-1 NaCl Neutral Solutions
Nanomaterials have gained significant attention due to their unique properties,leading to extensive research in this field.Nano-sized and conventionally sized powders were prepared through mechanical alloying(MA)and powder metallurgy(PM)techniques in experiments.By controlling factors such as temperature and pressure,both sizes of Cu-20Co-20Cr-20Ni powders were consolidated into bulk alloys using a vacuum hot-press sintering furnace.The corrosion behavior of these alloys and the impact of nanocrystallization were studied using electrochemical tests in 0.5 mol·L-1 neutral NaCl solution.The results indicated that when Cu-20Co-20Cr-20Ni alloy was exposed to a 0.5 mol·L-1 NaCl corrosive solution,the nanosized Cu-20Co-20Cr-20Ni alloy exhibited a positive shift in its self-corrosion potential compared to the corresponding conventional-sized alloy.Furthermore,the charge transfer resistance increased,and the corrosion current density decreased for the nanosized alloy.Therefore,it can be concluded that grain refinement can enhance the corrosion resistance properties of Cu-20Co-20Cr-20Ni alloy.

NanocrystallineCorrosion electrochemistryMechanical alloyingCu-Co-Cr-Ni alloy

张昊鑫、王晴、曹中秋、张轲、王艳

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沈阳师范大学 化学化工学院,辽宁 沈阳 110034

纳米晶 腐蚀电化学 机械合金化法 Cu-Co-Cr-Ni合金

辽宁省重点研发计划

2018304025

2024

辽宁化工
辽宁省化工学会

辽宁化工

影响因子:0.234
ISSN:1004-0935
年,卷(期):2024.53(5)
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