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不同无机抗菌体系对聚乙烯供水管材抗菌性能的影响

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采用双螺杆挤出机将聚乙烯(PE100)分别和纳米氧化锌(15 nm粒径和30 nm粒径)、纳米银、纳米二氧化钛进行熔融共混制备出抗菌PE管材料,并测试了抗菌性能、DSC、拉伸性能和冲击性能.结果表明:纳米氧化锌和纳米银的抗菌体系优于二氧化钛的抗菌体系;15 nm ZnO质量分数0.150%的复合材料对大肠杆菌的抗菌率高于 99.9%,30 nm ZnO 质量分数 0.500%的复合材料对大肠杆菌的抗菌率为 99.7%,小尺寸的ZnO抗菌剂有更高的抗菌性能;添加了高含量抗菌剂(质量分数 1%的TiO2)复合材料的综合力学性能降低.
Effect of Different Inorganic Antimicrobial Systems on Antimicrobial Performance of PE Water Supply Pipes
Antibacterial PE pipe materials were prepared by melt blending polyethylene(PE100)with nano zinc oxide(15 nm particle size and 30 nm particle size),nano silver and nano titanium dioxide,respectively,using a twin-screw extruder.And the antibacterial properties,DSC,tensile properties and impact properties were tested.It was shown that,the antimicrobial system of ZnO nanoparticles and silver nanoparticles was better than that of titanium dioxide;the antimicrobial rate of the composites with 15 nm ZnO of mass fraction 0.150%against Escherichia coli was higher than 99.9%,and the antimicrobial rate of the composites with 30 nm ZnO of mass fraction 0.500%against Escherichia coli was 99.7%,and the small size of ZnO antimicrobial agent had higher antimicrobial performance;the overall mechanical properties of the composites with high content of antimicrobial agent(mass fraction 1%TiO2)were reduced.

PE100Inorganic antibacterial agentAntibacterial propertiesMechanical properties

马祥瑞、王伟、史颖

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沈阳化工大学高分子产业高端制造研究院,辽宁 沈阳 110142

沈阳化工大学 材料科学与工程学院,辽宁 沈阳 110142

PE100 无机抗菌剂 抗菌性能 力学性能

2024

辽宁化工
辽宁省化工学会

辽宁化工

影响因子:0.234
ISSN:1004-0935
年,卷(期):2024.53(5)
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