辽宁化工2024,Vol.53Issue(7) :993-996.

占空比对脉冲电镀Ni-Co-Al2O3-WS2复合镀层摩擦学性能的影响

Effect of Pulse Duty Cycle on Tribological Properties of Ni-Co-Al2O3-WS2 Composite Coating

赵朗 金浩 陶绍虎 吕镖 柳泉 郭策安
辽宁化工2024,Vol.53Issue(7) :993-996.

占空比对脉冲电镀Ni-Co-Al2O3-WS2复合镀层摩擦学性能的影响

Effect of Pulse Duty Cycle on Tribological Properties of Ni-Co-Al2O3-WS2 Composite Coating

赵朗 1金浩 1陶绍虎 1吕镖 2柳泉 1郭策安1
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作者信息

  • 1. 沈阳理工大学,辽宁 沈阳 110159
  • 2. 太原卫星发射中心,山西 忻州 036304
  • 折叠

摘要

为提高 CrNi3MoVA 钢的耐磨性能,用脉冲电沉积法在 CrNi3MoVA 钢表面制备了Ni-Co-Al2O3-WS2 复合镀层,利用扫描电镜(SEM)和 X 射线衍射仪(XRD)分析镀层的表面形貌和物相结构,用纳米压痕仪和往复式摩擦磨损试验机测试镀层的纳米力学性能与摩擦学性能.结果表明:Ni-Co-Al2O3-WS2复合镀层表面呈结节状凸起,随着占空比的增加,镀层表面结节密度减少,(111)晶面择优取向更加明显.占空比为 0.1 的复合镀层拥有最高的硬度 7.24 GPa,最低的平均摩擦系数 0.38和体积磨损率1.52×10-4 mm3·(N·m)-1.镀层中的n-Al2O3颗粒会支撑在摩擦面上减少摩擦副间的接触面积,同时与n-WS2颗粒与在剪切作用下脱落形成润滑膜,发挥协同减磨作用提高镀层摩擦学性能.

Abstract

Ni-Co-Al2O3-WS2 composite coating was prepared on the surface of CrNi3MoVA steel by pulse electrodeposition to improve the wear resistance of CrNi3MoVA steel.The surface morphology and phase structure of the coating were analyzed using scanning electron microscopy(SEM)and X-ray diffraction(XRD),and the nano mechanical and tribological properties of the coating were tested using a nanoindentation instrument and a reciprocating friction and wear tester.The results showed that the surface of the Ni-Co-Al2O3-WS2 composite coating exhibited nodular protrusions.With the increase of the duty cycle,the density of nodules on the coating surface decreased,and the preferred orientation of the(111)crystal plane became more obvious.The composite coating with a duty cycle of 0.1 had the highest hardness of 7.24 GPa,the lowest average friction coefficient of 0.38,and a wear rate of 1.52×10-4 mm3·(N·m)-1.The n-Al2O3 particles in the coating can support on the friction surface to reduce the contact area between the friction pairs,and at the same time,they can detach with the n-WS2 particles under shear to form a lubricating film,exerting a synergistic anti wear effect to improve the tribological performance of the coating.

关键词

Ni-Co-Al2O3-WS2复合镀层/脉冲电沉积/占空比/摩擦学性能

Key words

Ni-Co-Al2O3-WS2 composite coating/Pulse electrodeposition/Duty cycle/Tribological properties

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基金项目

辽宁省科技厅应用基础研究计划(2023020243-JH2/1013)

2023年辽宁省教育厅基本科研项目(JYTMS20230191)

出版年

2024
辽宁化工
辽宁省化工学会

辽宁化工

影响因子:0.234
ISSN:1004-0935
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