首页|熔盐法辅助制备淀粉基生物炭材料电化学性能研究

熔盐法辅助制备淀粉基生物炭材料电化学性能研究

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采用KCl和NaCl混合盐,在熔融的状态下对淀粉前驱物进行炭化、活化双功能改性,在空气气氛中用马弗炉对其进行修饰,节省大量的惰性气体.熔融盐通过刻蚀效应在材料表面形成分级孔结构,高的比表面积和丰富的孔结构能够提高活性炭的电化学性能.在0.5 A·g-1 的电流密度下,CMS-3的容量为230 F·g-1,组装成对称电容器在电流密度为 0.5 A·g-1 时的比电容为155 F·g-1,展现了良好的电化学性能.此外,CMS-3还表现出优异的循环寿命,10 000次循环后的高容量保持率为99.4%.
Study on Electrochemical Properties of Starch-Based Biochar Materials Prepared by Molten Salt Method
The mixed salt of KCl and NaCl was used to carbonize and activate the starch precursor in molten state,and it was modified by muffle furnace in air atmosphere,which saved a lot of inert gas.The fused salt formed a hierarchical pore structure on the surface of the material through etching effect.The high specific surface area and abundant pore structure could improve the electrochemical performance of activated carbon.At the current density of 0.5A·g-1,the capacity of CMS-3 was 230 F·g-1.The assembled symmetrical capacitor had the current density of 0.5 A·g-1 and the specific capacitance of the symmetrical device was 155 F·g-1,showing good electrochemical performance.In addition,CMS-3 showed excellent cycle life,with a high volume retention rate of 99.4%after 10 000 cycles.

StarchMolten salt processSupercapacitorPorous carbon

温美惠、苏畅、赵婷婷

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沈阳化工大学化学工程学院,辽宁 沈阳 110142

淀粉 熔盐法 超级电容器 多孔炭

2024

辽宁化工
辽宁省化工学会

辽宁化工

影响因子:0.234
ISSN:1004-0935
年,卷(期):2024.53(7)