室温合成UiO-66-NH2(Zr)的MOF材料及其对头孢克肟的吸附性能
Synthesis of UiO-66-NH2(Zr)MOF Material at Room Temperature and Its Adsorption Property to Cefixime
王妍 1邱志芳 1唐贵琴 1黄余改1
作者信息
- 1. 江苏第二师范学院生命科学与化学化工学院,江苏 南京 211200
- 折叠
摘要
通过一步法在室温下合成了NH2 功能化的Zr-MOF(UiO-66-NH2)材料,并利用 X射线单晶衍射分析和红外光谱对其结构进行了表征.合成的 UiO-66-NH2(Zr)对抗生素头孢克肟有很好的吸附,以 UiO-66-NH2(Zr)的荧光猝灭信号为指标,探究了不同条件下的吸附性能.结果表明:在pH=6.5的磷酸缓冲溶液中,在0.2 mg·mL-1 的吸附剂上,头孢质量浓度在0.01～2.00 mg·mL-1 时,荧光猝灭程度随着头孢的质量浓度增加呈线性关系.
Abstract
The NH2-functionalized Zr-MOF(UiO-66-NH2)material was synthesized by one-step method at room temperature.X-ray single crystal diffraction analysis and infrared spectroscopy was used to characterize the structure.The synthesized UiO-66-NH2(Zr)had good adsorption property to the antibiotic cefixime.The adsorption properties under different conditions was investigated by the fluorescence quenching of UiO-66-NH2(Zr).The results indicated that in phosphate buffer solution with pH=6.4,the fluorescence quenching showed a linear relationship with the increase of cefixime mass concentration at the range of 0.01～2.00 mg·mL-1 on 0.2 mg·mL-1 adsorbent.
关键词
Zr-MOF/UiO-66-NH2/荧光猝灭/头孢克肟Key words
Zr-MOF/UiO-66-NH2/Fluorescence quenching/Cefixime引用本文复制引用
基金项目
国家级大学生创新创业训练计划项目(202214436013Z)
2022年江苏省高等学校大学生创新创业训练项目(202214436013Z)
出版年
2024
NETL
NSTL
万方数据