含膦多孔有机聚合物的合成及其在催化反应中的应用研究进展
Research Progress in Synthesis of Porous Organic Polymers Containing Phosphine and Their Applications in Catalytic Reactions
刘子奇 1孙树辉 1贾肖飞1
作者信息
- 1. 青岛科技大学化学与分子工程学院,山东 青岛 266042
- 折叠
摘要
含膦多孔有机聚合物不仅具有高的表面积、稳定的骨架结构和良好的结构修饰性等优良特性,而且聚合物中高浓度的膦配体单元能有效负载金属.因此含膦多孔有机聚合物负载过渡金属催化的非均相反应引起了广泛的关注.综述了含膦多孔有机聚合物的合成方法及其在氢甲酰化反应、氢化反应、氢硅化反应、氧化羰基化反应、Suzuki 偶联反应等方面的应用,最后对该类材料的发展前景进行了展望.
Abstract
The porous organic polymer containing phosphine not only has high surface area,stable structure and good modification,but also the high concentration of phosphine ligand units in the polymer can effectively load metal.Therefore,heterogeneous reactions catalyzed by phosphine-containing porous organic polymers supported-transition metals have attracted extensive attention.In this paper,the synthesis methods of various phosphine-containing porous organic polymers and their applications in hydroformylation,hydrogenation,hydrosilylation,oxycarbonylation and Suzuki coupling reactions were reviewed.The development prospect of these materials was also prospected.
关键词
多孔有机聚合物/非均相催化/合成方法/过渡金属Key words
Porous organic polymer/Heterogeneous catalysis/Synthetic method/Transition metal引用本文复制引用
出版年
2024
NETL
NSTL
万方数据