Research Progress in Synthesis of Porous Organic Polymers Containing Phosphine and Their Applications in Catalytic Reactions
The porous organic polymer containing phosphine not only has high surface area,stable structure and good modification,but also the high concentration of phosphine ligand units in the polymer can effectively load metal.Therefore,heterogeneous reactions catalyzed by phosphine-containing porous organic polymers supported-transition metals have attracted extensive attention.In this paper,the synthesis methods of various phosphine-containing porous organic polymers and their applications in hydroformylation,hydrogenation,hydrosilylation,oxycarbonylation and Suzuki coupling reactions were reviewed.The development prospect of these materials was also prospected.
Porous organic polymerHeterogeneous catalysisSynthetic methodTransition metal
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