辽宁化工2024,Vol.53Issue(11) :1653-1657.

高性能铵离子电池用乙酸铵电解液制备

Preparation of Ammonium Acetate Electrolyte for High-Performance Ammonium Ion Batteries

贾靖宇 南文阳 冯心如 高昕悦 李若琪 田然
辽宁化工2024,Vol.53Issue(11) :1653-1657.

高性能铵离子电池用乙酸铵电解液制备

Preparation of Ammonium Acetate Electrolyte for High-Performance Ammonium Ion Batteries

贾靖宇 1南文阳 1冯心如 1高昕悦 1李若琪 1田然1
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作者信息

  • 1. 华北理工大学化学工程学院,河北 唐山 063210
  • 折叠

摘要

研究了采用3,4,9,10-四甲酰二亚胺(PTCDI)模拟负极的乙酸铵电解质来实现高性能铵离子电池.本研究发现,由于高铵离子含量抑制了离子传输并阻碍了铵离子嵌入/脱出PTCDI电极,因此最高浓度的电解质并不具有最佳的电化学性能.研究给出了一个新的结果,即"盐包水"电解质可能不是最佳的性能,并提供了合适的电解质应平衡离子传输的方法.

Abstract

In this article,3,4,9,10-tetramethylenediamine(PTCDI)was used as a simulated negative electrode in ammonium acetate electrolyte to achieve high-performance ammonium ion batteries.The results showed that because the high content of ammonium ions inhibited ion transport and hindered the insertion/removal of ammonium ions in PTCDI electrodes,the electrolyte with the highest concentration did not have the best electrochemical performance.This study presents a new result that"salt in water"electrolytes may not be the optimal performance,and provides a suitable method for balancing ion transport in electrolytes.

关键词

铵离子/PTCDI/盐包水/电解质/电化学性能

Key words

Ammonium ion/PTCDI/Salt in water/Electrolyte/Electrochemical performance

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出版年

2024
辽宁化工
辽宁省化工学会

辽宁化工

影响因子:0.234
ISSN:1004-0935
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