首页|热电池LiV3O8/NiF2复合正极材料放电性能的研究

热电池LiV3O8/NiF2复合正极材料放电性能的研究

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通过溶胶凝胶法合成了钒酸锂正极材料,并与不同比例的氟化镍共混,采用粉末压片工艺制备单体电池,确定了LiV3O8/NiF2 正极材料最佳比例.结果表明:单体电池以 100 mA·cm-2 恒流放电时,9∶1 放电性能最优,正极中电解质和导电剂的最佳分数分别 15%和 15%.在起始放电电压为2.565 4 V、截止电压为2 V时比容量为140 mA·h·g-1.
Study on Discharge Performance of LiV3O8/NiF2 Cathode Materials for Thermal Batteries
Lithium vanadate cathode material was synthesized by sol-gel mothod,and mixed with nickel fluoride in different proportions,the single battery was prepared by powder compression process,and the optimal proportion of LiV3O8/NiF2 cathode material was determined.The experimental results showed that when the single cell battery was discharged at a constant current of 100 mA·cm-2,the discharge performance of the single battery with 9∶1 was the best,and the optimal addition amounts of electrolyte and conductive agent in the cathode were 15%and 15%,respectively.The specific capacity was 140 mA·h·g-1 when the initial discharge voltage was 2.565 4 V and the cutoff voltage was 2 V.

Thermal batteryLithium vanadateNickel fluorideDischarge performance

杨倩、杨少华、赵平、董华

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沈阳理工大学,辽宁 沈阳 110158

辽宁省特种储备电源专业技术创新中心,辽宁 沈阳 110158

西北工业集团有限公司,陕西 西安 710043

热电池 钒酸锂 氟化镍 放电性能

2024

辽宁化工
辽宁省化工学会

辽宁化工

影响因子:0.234
ISSN:1004-0935
年,卷(期):2024.53(11)