首页|2015年华北地区上甸子大气本底站PM2.5化学组分特征及来源分析

2015年华北地区上甸子大气本底站PM2.5化学组分特征及来源分析

Characteristics and source analysis of PM2.5 chemical components at the Shangdianzi regional background station in North China in 2015

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根据2015年上甸子区域大气本底站PM2.5样品采集数据,分析PM2.5质量浓度及其化学组分变化特征,应用质量闭合、后向轨迹、潜在源等方法分析其来源.结果表明:2015年上甸子站PM2.5质量浓度年平均值为44.9 μg·m-3,春季、夏季、秋季、冬季均值分别为 58.1、30.9、39.7、51.3 μg·m-3,与 2009-2010 年相比分别降低了 33%、56%、46%、9%.SO42-、NO3-和NH4+质量浓度年平均值分别为8.5±9.2、6.4±8.3、3.9±4.7 μg·m-3,有机碳、元素碳浓度年平均值分别为8.9±6.3 μg·m-3、1.6± 1.2 μg·m-3.NO3-与SO2-浓度日均值的比值为0.82,大于2004年、2012年和2013年的观测结果.PM25的主要组分为土壤、有机物、硫酸盐、硝酸盐,占比分别为34%、23%、22%、15%.与2004年相比,上甸子站PM2.5中硫酸盐占比有所下降,土壤组分占比提高.上甸子站PM2.5主要源自站点南部及西北部、北部等,河北省、山东省等地的区域传输对上甸子站高浓度PM2.5存在较大影响.
Based on the PM2.5 sample data collected from Shangdianzi regional atmospheric background station in 2015,the variation characteristics of PM2.5 mass concentration and its chemical components were analyzed,and its sources were traced by mass closure,backward trajectory,and potential source contribution methods.The results show that the annual average PM2.5 mass concentration at Shangdianzi station in 2015 was 44.9 μg·m-3,with aver-age concentrations of 58.1 µg·m-3 in spring,30.9 μg·m-3 in summer,39.7 μg·m-3 in autumn,and 51.3 μg·m3 in winter.Compared with 2009 to 2010,they decreased by 33%,56%,46%,and 9%respectively.The annual aver-age mass concentrations of SO4-,NO3-and NH4+are 8.5±9.2,6.4±8.3,and 3.9±4.7 μg·m-3,respectively.The average annual concentrations of organic carbon and elemental carbon are 8.9±6.3 μg·m-3 and 1.6± 1.2 μg·m-3,respectively.The daily average concentration ratio of NO3-to SO42-is 0.82,which is higher than the observed results in 2004,2012 and 2013.The main components of PM2.5 are soil,organic matter,sulfates,and ni-trates,accounting for 34%,23%,22%,and 15%,respectively.Compared with 2004,the proportion of sulfate in PM2.5 at Shangdianzi station has decreased,while the proportion of soil components has increased.The PM2.5 at Shangdianzi station primarily originates from the southern,northwestern,and northern of the station,and regional transmission from Hebei and Shandong provinces has a great impact on the high concentration of PM2.5 in Shangdi-anzi Station.

AerosolChemical compositionBackward trajectory

贾小芳、李杨、孙晓晴、董璠

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中国气象局气象探测中心,北京 100081

中国气象局京津冀环境气象预报预警中心,北京 100089

气溶胶 化学组分 后向轨迹

国家自然科学基金面上项目

42175189

2023

气象与环境学报
中国气象局沈阳大气环境研究所

气象与环境学报

CSTPCD
影响因子:1.433
ISSN:1673-503X
年,卷(期):2023.39(6)
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