首页|嘉兴市大气VOCs特征及其对臭氧生成的影响研究

嘉兴市大气VOCs特征及其对臭氧生成的影响研究

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为研究嘉兴市大气VOCs特征及其对臭氧生成的影响,采集了 2022年1月、4月、7月和10月大气中114种VOCs物种,分析VOCs的浓度分布与组成特征,估算其臭氧生成潜势(OFP)。结果表明:嘉兴市大气VOCs平均体积浓度为38。74×10-9,OVOCs占比最高,各组分的体积浓度都在冬季呈现最高值。OPF均值为256。76μg/m3,芳香烃在各季节的OFP都最大,对OFP贡献最大的物种为甲苯、间/对—二甲苯、乙烯、丙烯、乙醛等,削减机动车排放和溶剂使用是嘉兴市控制O3污染的关键。通过计算X/E(间/对—二甲苯和乙苯的体积浓度之比)和T/B(甲苯和苯的体积浓度之比),得出气团存在长距离传输现象,且受到溶剂挥发等VOCs排放源的影响更显著。
Characteristics of Atmospheric VOCs and Their Effects On Ozone Generation in Jiaxing City
In order to study the characteristics of atmospheric VOCs and their effects on ozone generation in Jiax-ing City,114 VOCs species in the atmosphere in January,April,July and October 2022 were collected;the con-centration and composition characteristics of VOCs were analyzed;and their ozone formation potential(OFP)was estimated.The results showed that the average volume concentration of atmospheric VOCs in Jiaxing city was 38.74X 10-9,and the proportion of OVOCs was the highest.The volume concentration of each component was the highest in winter.The average OPF in Jiaxing city was 256.76 μg/m3,and the OFP of aromatic hydrocarbons was the highest in all seasons.The VOCs species that contributed the most to OFP were toluene,m-p-xylene,ethylene,propylene,acetaldehyde,etc.Reducing vehicle emissions and solvent use is the key to controlling O3 pollution in Jiaxing City.By calculating X/E(volume concentration ratio of m-p-xylene to ethylbenzene)and T/B(volume concentration ratio of toluene to benzene),it is concluded that the air mass has a long-distance transport,and it was more significantly affected by VOCs emission sources such as solvent volatilization.

VOCsozoneozone formation potential(OFP)volume concentrationJiaxing city

陈建挺、富英杰、熊传芳

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嘉兴市智慧环保与机动车污染防治中心,浙江嘉兴 314000

嘉兴市生态环境应急监控与事故调查中心,浙江嘉兴 314000

VOCs 臭氧 臭氧生成潜势 体积浓度 嘉兴市

浙江省生态环境科研和成果推广项目嘉兴市民生科技创新研究项目

2022HT00212023AD31071

2024

绿色科技
花木盆景杂志社

绿色科技

影响因子:0.365
ISSN:1674-9944
年,卷(期):2024.26(6)
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