首页|镁系CO2电池系统对CO2存储转化性能的影响研究

镁系CO2电池系统对CO2存储转化性能的影响研究

扫码查看
目前航运业能源消耗和碳排放日益严峻,为降低船舶温室气体排放,实现航运业碳减排中长期战略目标,CO2捕集和封存技术(CCS)技术成为重要手段。然而该技术在液化和存储阶段存在能耗高、占据空间大,运输处理成本高等问题,因此开发低能耗、紧凑化CO2储存技术是推动船舶CCS技术发展的关键。基于此,介绍了一种镁系二氧化碳电池系统,将CO2转化利用,在实现CO2储存的同时也能产生氢气等新型能源。通过高效催化电极的制备和电解液,CO2流量对电池性能影响的测试研究,最终确定最佳的工艺参数为电极采用Pd/CeO2-oct,电解质为0。5 mol/L NaOH溶液,CO2流量为1 L/h,电池系统展现出在8 mA/cm2电流密度下循环600 min(20个充放电循环)的高循环稳定性,产氢量为10。135 mL,法拉第效率达到97。03%。
Research on the Influence of Magnesium Based Carbon Dioxide Battery System on Carbon Dioxide Conversion Performance
At present,energy consumption and carbon emissions in the shipping industry are becoming increasing-ly severe.In order to reduce greenhouse gas emissions from ships and achieve the medium-and long-term strategic goals of carbon reduction in the shipping industry,CO2 capture and storage technology(CCS)has become an im-portant means.However,this technology has problems such as high energy consumption,large space occupation,and high transportation and processing costs in the liquefaction and storage stages.Therefore,developing low en-ergy and compact CO2 storage technology is the key to promoting the development of ship CCS technology.This paper introduces a magnesium based carbon dioxide battery system that converts and utilizes CO2,achieving CO2 storage while also producing new energy sources such as hydrogen.Through the preparation of efficient catalytic electrodes and the testing of the effect of CO2 flow rate on battery performance,the optimal process parameters were determined to be Pd/CeO2 oct electrode,0.5mol/L NaOH electrolyte solution,and CO2 flow rate of lL/h.The battery system exhibited high cycling stability under a current density of 8mA/cm2 for 600 minutes(20 charge dis-charge cycles),with a hydrogen production of 10.135mL and a Faraday efficiency of 97.03%.

carbon dioxidebatteriescatalysisconversion efficiency

李圣军、魏冕、杨浩然、李珂、姚宇翔

展开 >

中国船级社上海分社,上海 200135

上海船用柴油机研究所,上海 200090

CO2 电池 催化 转化效率

2024

绿色科技
花木盆景杂志社

绿色科技

影响因子:0.365
ISSN:1674-9944
年,卷(期):2024.26(6)
  • 22